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玉米秸秆常压液化条件的研究

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随着现代技术的进步,玉米秸秆(CS)等农业废弃物的处理将不再以焚烧为主要方式,而是经过常压液化来实现生物质的增值转化,改善生态环境.采用单因素法,分别探讨了不同液化剂、液化时间、液化温度、液固比、催化剂对液化产率和液化产物中甘醇含量的影响,以优化其工艺.通过气相色谱质谱(GC-MS)和傅里叶红外光谱(FTIR)对液化产物进行分析,结果表明,当液化温度为160 ℃,液化时间60 min,液化剂为聚乙二醇400∶乙二醇(PEG400∶EG)=7∶3,液化剂与玉米秸秆的液固比为10∶1,催化剂选用浓硫酸时,液化效果最佳.
Study on the Liquefaction Conditions for Corn Straw under Atmospheric Pressure
With the progress of modern technology,the treatment of agricultural wastes such as corn straw(CS)is no longer based on incineration as the main way,but through atmospheric pressure liquefaction to realize the value-added transformation of corn straw and improve the ecological en-vironment.The effects of different liquefaction agents,liquefaction time,liquefaction temperature,liquid-solid ratio and catalyst on the liquefaction yield and the glycol content in liquefaction products are investigated by single factor method in order to optimize the process.The liquefied products are characterized by gas chromatography mass spectrometry(GC-MS)and Fourier transform infrared spectroscopy(FTIR).The results show that the liquefaction effect is best when the liquefaction agent is polyethylene glycol 400 and ethylene glycol with a ratio(PEG400∶EG)of 7∶3,the liquid-solid ratio of liquefaction agent to corn straw is 10∶1,and the concentrated sulfuric acid catalyzes the liquefaction at 160 ℃ for 60 min.

corn strawliquefaction under atmospheric pressureFTIRGC-MS

于晶晶、娄春华、王慧晓、杨雨鑫

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齐齐哈尔大学化学与化学工程学院,黑龙江 齐齐哈尔 161006

齐齐哈尔大学黑龙江省聚合物基复合材料重点实验室,黑龙江 齐齐哈尔 161006

玉米秸秆 常压液化 FTIR GC-MS

2025

化学与粘合
黑龙江省化学学会 黑龙江省科学院石油化学研究院

化学与粘合

影响因子:0.386
ISSN:1001-0017
年,卷(期):2025.47(1)