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磁化改性吸附剂在选矿废水污染物净化与利用中的应用

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选取我国某个铅锌类选矿企业尾砂库为研究区,采集尾砂库中的综合性废水,经处理后作为废水样本使用,并制备磁化改性硅藻基吸附剂与磁化改性活性炭吸附剂,通过扫描电镜、高性能比表面积孔径分析仪、X射线衍射仪,获取两种磁改吸附剂的电镜图、比表面积、孔径、XRD谱图,分析磁化改性吸附剂磁性.而后通过向选矿废水样本中投入磁化改性吸附剂,测量与对比选矿废水吸附处理前后污染物含量,分析与验证磁化改性吸附剂在选矿废水污染物净化与利用中的应用效果.经过实验分析可知:磁化后的硅藻基吸附剂与活性炭吸附剂比表面积提高了21.023 m2/g,硅藻土磁化改性后孔径大小由11.901 nm缩小至10.009 nm,中孔率更高,并拥有多个衍射峰,能够使磁性元素成功沉积于硅藻土以及活性炭的表面,获得更多磁性;对于选矿废水污染方面,磁化改性吸附硅藻基吸附剂与磁化改性活性炭吸附剂对Cu和Pb的净化效果最为明显.Cu污染从1.02 mg·L-1降低至0.04 mg·L-1,Pb污染从9.15 mg·L-1降低至0.31 mg·L-1,可为选矿废水净化与利用提供有效支持与保障.
Research on the Interfacial Bonding Performance of Flame Retardant Polyurethane External Wall Insulation Board
A tailings pond of a certain lead-zinc beneficiation enterprise in China is selected as the research area,the comprehensive wastewater is collected from the tailings pond and used as the wastewater sample after treatment.The magnetized modified diatomaceous adsorbents and magne-tized modified activated carbon adsorbents are prepared.The electron microscopy images,specific surface area,pore size and XRD patterns of the two kinds of magnetic modified adsorbents are obtained through scanning electron microscopy,high-performance specific surface area pore size analyzer and X-ray diffraction instrument,and the magnetic properties of the adsorbents are analyzed.Then,by adding magnetized modified adsorbents to the wastewater samples,the pollutant content before and after adsorption treatment of ore dressing wastewater is measured and compared,and the applica-tion effect of magnetized modified adsorbents in the purification and utilization of pollutants in ore dressing wastewater is analyzed and verified.After experimental analysis,it is found that the specific surface area of the magnetized diatomaceous adsorbent increases by 21.023 m2/g compared to that of the activated carbon adsorbent.After magnetic modification,the pore size of diatomaceous earth decreases from 11.901 nm to 10.009 nm with a higher mesopore ratio and multiple diffraction peaks.This enables magnetic elements to successfully deposit on the surface of diatomaceous earth and acti-vated carbon,obtaining more magnetism;For the pollution of mineral processing wastewater,magnetic modified diatomaceous adsorbents and magnetic modified activated carbon adsorbents have the most significant purification effects on Cu and Pb.The reduction of Cu pollution from 1.02 mg·L-1 to 0.04 mg·L-1 and Pb pollution from 9.15 mg·L-1 to 0.31 mg·L-1 can provide effective support and guarantee for the purification and utilization of min-eral processing wastewater.

magnetic modificationadsorbentmineral processing wastewaterpollutant purificationdiatomaceous earth natural soilactivated carbon

石宝兴

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青海昆仑黄金有限公司,青海海西 816101

磁化改性 吸附剂 选矿废水 污染物净化 硅藻土原土 活性炭

2025

化学与粘合
黑龙江省化学学会 黑龙江省科学院石油化学研究院

化学与粘合

影响因子:0.386
ISSN:1001-0017
年,卷(期):2025.47(1)