首页|莺琼盆地高温高含CO2环境水泥石腐蚀规律及机理研究

莺琼盆地高温高含CO2环境水泥石腐蚀规律及机理研究

扫码查看
莺琼盆地部分井高压井段地层的CO2 含量高,针对高温高含CO2 条件下,水泥环强度衰退和CO2 腐蚀导致的水泥石强度降低规律和机理不清楚等问题.采用实验方法分析了腐蚀时间、温度、压力及CO2 分压等因素对水泥石的腐蚀规律的影响并分析了腐蚀机理.结果表明:随着腐蚀时间、温度、CO2 分压、地层压力的增加,水泥石的腐蚀深度增加,同时抗压强度降低,产生这种现象主要原因是CO2 溶于水后会腐蚀水泥石中的雪硅钙石和硬硅钙石,生成在潮湿的CO2 环境下易溶的碳酸氢钙,使得水泥石孔隙度和渗透率增大,强度降低.该研究为后续高温高压井固井水泥浆体系选择及改进提供了依据.
Study on the Corrosion Pattern and Mechanism of Cement in High Temperature and High CO2 Environment in Yingqiong Basin
Due to the high CO2 content in high-pressure sections of some wells in Yingqiong Basin,the strength degradation of cement sheath and the mechanism of strength reduction of cement caused by CO2 corrosion are not clear under the condition of high temperature and high CO2 content,the effects of corrosion time,temperature,pressure and CO2 partial pressure on the corrosion of cement were analyzed by experimental method,and the corrosion mechanism was analyzed.The results show that with the increase of corrosion time,temperature,CO2 partial pressure and formation pressure,the corrosion depth of cement increases,while the compressive strength decreases.The main reason for this phenomenon is that CO2 dissolved in water corrodes tobermorite and xonorite in cement,generating calcium bicarbonate which is easily soluble in moist CO2 environment,so that the porosity and permeability of cement increase and the strength decrease.This study provides a basis for the selection and improvement of cement slurry system for subsequent high temperature and high pressure wells.

cementhigh temperaturehigh CO2 contentcrystal transformationcalcium carbonate

邱康、崔强、熊振宇、王颖、范鸿飞

展开 >

中石化海洋石油工程有限公司,上海 200120

西南石油大学,四川成都 610500

水泥石 高温 高含CO2 晶体转变 碳酸钙

2024

海洋石油
中国石油化工股份有限公司上海海洋油气分公司

海洋石油

影响因子:0.325
ISSN:1008-2336
年,卷(期):2024.44(2)