火炸药学报2024,Vol.47Issue(2) :172-179.DOI:10.14077/j.issn.1007-7812.202305010

丁羟三组元推进剂的增材制造及性能研究

Study on Additive Manufacturing and Performance of HTPB Tripropellant

孙鑫科 石柯 史钰 罗聪 王鼎程 李伟 任全彬
火炸药学报2024,Vol.47Issue(2) :172-179.DOI:10.14077/j.issn.1007-7812.202305010

丁羟三组元推进剂的增材制造及性能研究

Study on Additive Manufacturing and Performance of HTPB Tripropellant

孙鑫科 1石柯 1史钰 1罗聪 1王鼎程 1李伟 1任全彬2
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作者信息

  • 1. 航天化学动力技术重点实验室 湖北 襄阳 441003;湖北航天化学技术研究所,湖北 襄阳 441003
  • 2. 航天动力技术研究院,陕西 西安 710025
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摘要

针对传统浇注成型与直写式 3D 打印对固体推进剂药浆工艺性能要求相冲突的问题,为实现小型药柱的3D打印,采用添加少量定型助剂(YJ)的方法对丁羟三组元推进剂配方进行改性,对改性前后推进剂的工艺性能、力学性能、燃烧性能和能量性能进行对比分析,并探究了YJ 对推进剂性能的影响.结果表明,改性后的推进剂药浆具备可控挤出和室温堆积的流变特性;YJ 的加入使得推进剂在 20、70℃下的最大抗拉强度分别降低 0.1 和 0.15 MPa,断裂伸长率分别增加了 12.7%和 9.9%,表明YJ 对其力学性能影响显著;此外,实验及理论计算表明,YJ 对推进剂的燃烧性能和能量性能影响甚微,燃速最大降低 0.24 mm/s,能量变化幅度均在 1%以内;表明定型助剂(YJ)的加入不仅使药浆满足 3D打印要求,而且对原始推进剂的整体性能没有显著负面影响.

Abstract

In order to address the conflict between traditional casting molding and direct writing 3D printing in terms of the process performance of solid propellant slurry,the HTPB propellant slurry was modified through the addition of a small amount of setting agent(YJ)to enable the 3D printing of small propellant grain.To examine the of YJ on the propellant's properties,a comparison and analysis of the performance,mechanical performance,combustion performance,and performance of the pro-pellant was conducted before and after modification.The results indicate that the modified propellant slurry exhibits controllable extrusion and room temperature accumulation.The addition of YJ decreases the maximum tensile strength of the propellants by 0.1 and0.15 MPa at 20 and 70℃ respectively,and the elongation at break increases by 12.7% and 9.9% respectively.This evidence demonstrates that YJ significantly affects the mechanical properties of the propellants.Furthermore,both experi-mental and theoretical calculations indicate that YJ has minimal impact on the combustion and energy performance of the propel-lant.The burning rate is reduced by a maximum of 0.24mm/s,and the energy variation range is less than 1%.The addition of the setting agent(YJ)not only enables the slurry to meet the requirements for 3D printing but also has no significant the overall performance of the original propellant.

关键词

复合固体推进剂/丁羟三组元推进剂/增材制造/力学性能/流变特性/燃烧性能/3D打印

Key words

composite solid propellant/HTPB tripropellant/additive manufacturing/mechanical properties/rheological prop-erties/combustion performance/3D printing

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基金项目

国家自然科学基金(22275051)

科技部重点研发计划资助(2022YFB4603100)

出版年

2024
火炸药学报
中国兵工学会 中国兵器工业第204研究所

火炸药学报

CSTPCD北大核心
影响因子:0.841
ISSN:1007-7812
参考文献量20
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