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快速泄压下含草酸铵HTPB推进剂的燃烧行为

Combustion Behavior of HTPB Propellant Containing Ammonium Oxalate under Rapid Depressurization

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为研究一系列含草酸铵(质量分数0~4%)的低燃速推进剂的燃熄可控特性,分别使用高压激光点火平台和磁吸式泄压试验发动机测定了其在稳态和瞬态下的燃烧参数,主要包括稳态燃速、临界泄压熄火边界和瞬态火焰变化过程.结果表明,随着泄压前初始压力(p0)的增加,推进剂泄压熄火所需的临界泄压速率(dp/dt)发生线性变化;向HTPB/AP推进剂中引入质量分数2%的草酸铵后,0.5~2.51 MPa内的泄压复燃区域缩小18.74%,所需的临界泄压熄火速率降低6.87%~25.18%;0.1~9MPa下的稳态燃速降低6.5%~20.5%,并在草酸铵质量分数为4%的配方中增至13.9%~26.6%.稳态燃烧和瞬态燃烧结果间的一致性表明,草酸铵的引入有利于HTPB/AP基推进剂泄压后达成熄火,这可归因于其对AP分解的强烈抑制和较大的分解吸热作用.
In order to investigate the controllability of ignition and extinguishment of a series of low burning rate propellants containing ammonium oxalate(mass fraction 0-4%),the combustion parameters of the propellants under steady-state and transient conditions were measured by using a high pressure laser ignition platform and a magnetic pressure relief test engine re-spectively.The parameters included steady-state burning rates,critical depressurization extinguishment boundaries,and transi-ent flame evolution processes.The results show that the critical depressurization rate(dp/dt)required for propellant extin-guishment linearly increases with the initial pressure(p0).Adding 2%ammonium oxalate into HTPB/AP propellant,the depre-ssurization relief region reignition area within 0.5 MPa to 2.51 MPa is reduced by 18.74%and the critical depressurization rate is de-creased by 6.87%—25.18%.The steady-state burning rate decreased by 6.5%—20.5%in the range at 0.1-9MPa,and in-creased to 13.9%—26.6%in the formula with 4%ammonium oxalate.The consistency between steady-state and transient combus-tion results indicates that ammonium oxalate helps HTPB/AP-based propellants achieve extinguishment after depressurization.This effect is attributed to its strong inhibition of AP decomposition and significant decomposition heat absorption.

physical chemistrylow burning rate propellantrapid depressurizationtransient combustionammonium oxalateHTPB propellantburning rate inhibitorshigh pressure laser ignition platform

罗一民、王军红、夏语、郑文芳、徐森、吴星亮

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南京理工大学 化学与化工学院,江苏南京 210094

国家民用爆破器材质量检验检测中心,江苏 南京 210094

物理化学 低燃速推进剂 快速泄压 瞬态燃烧 草酸铵 HTPB推进剂 降速剂 高压激光点火平台

2024

火炸药学报
中国兵工学会 中国兵器工业第204研究所

火炸药学报

CSTPCD北大核心
影响因子:0.841
ISSN:1007-7812
年,卷(期):2024.47(12)