首页|环保型聚氨酯防水涂料的制备及性能研究

环保型聚氨酯防水涂料的制备及性能研究

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以水为固化剂,二苯基甲烷二异氰酸酯(MDI)、聚醚多元醇(DL-2000D、MN-3050D)、磺酸盐接枝聚酯二醇(BY-3306)、二羟甲基丁酸(DMPA)和填料等为原料成功合成了一种环保型的水固化聚氨酯防水涂料.讨论了聚醚多元醇种类、亲水扩链剂、气体吸收剂和水的添加量等对涂料性能的影响.结果表明,当聚醚三醇在聚醚混合物中的质量分数为 10%、BY-3306 替代聚醚二醇DL-2000D质量的15%或DMBA在体系中的质量分数为 0.8%、硅酸盐水泥质量分数为 8%、NCO基质量分数为4.5%时,得到的防水涂料在添加 15%水固化后,拉伸强度可达 4.27 MPa,断裂伸长率为678%,撕裂强度为24.57 N/mm.
Preparation and Performance of Environmentally Friendly Polyurethane Waterproof Coating
A environmentally friendly waterborne polyurethane waterproof coating was successfully synthesized using water as the curing agent,diphenylmethane diisocyanate(MDI),polyether polyol(DL-2000D and MN-3050D),sulfonate grafted polyester diol(BY-3306)or the hydrophilic chain extender dimethylol butyric acid(DMBA)and filler as raw materials.The effects of ratio of polyether polyols,dosage of hydrophilic polyester diol,kinds and dosage of gas absorbent and dosage of water on the properties of the coatings were investigated.The results showed that the obtained waterproof coating(after curing with 15%water)had a tensile strength of 4.27 MPa,an elongation at break of 678%and a tear strength of 24.57 N/mm when the mass fraction of polyether triol in polyols mixture was 10%,mass fraction of BY-3306 in polyether glycol and BY-3306 mixture was 15%,or mass fraction of DMBA in the coatings was 0.8%,and dosage of Portland cement was 8%and the NCO content was 4.5%.

water curingpolyurethanewaterproof coating

刘畅、亓帅、龚赛

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江苏苏博特新材料股份有限公司 高性能土木工程材料国家重点实验室 江苏南京 211103

水固化 聚氨酯 防水涂料

2024

聚氨酯工业
中国聚氨酯工业协会 江苏省化工研究所有限公司

聚氨酯工业

CSTPCD
影响因子:0.507
ISSN:1005-1902
年,卷(期):2024.39(1)
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