首页|超疏水SiO2@TPU多孔材料的制备及性能

超疏水SiO2@TPU多孔材料的制备及性能

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采用超声混合法和浸渍法制备疏水二氧化硅改性的热塑性聚氨酯(TPU)多孔材料(SiO2@TPU),讨论了改性后样品结构微观形貌、饱和吸附性能、油水分离和吸附动力学性能.结果表明:SiO2改性得到的SiO2@TPU多孔材料孔洞大小层次分明,呈现三维贯通的镂空球状分级多孔结构,且具有高的孔隙率和较宽的孔径分布;SiO2的负载形成特殊浸润性表层,达到超疏水标准;材料比表面积提高为改性前的2 倍,SiO2@TPU材料油水分离性能更优,吸附速率大幅提升.
Preparation and Performance of Superhydrophobic SiO2@TPU Porous Materials
Hydrophobic silica modified thermoplastic polyurethane(TPU)porous material(SiO2@TPU)was prepared by ultrasonic mixing method and impregnation method.The microstructure,saturation adsorption,oil-water separation and adsorption kinetics of the modified sample were discussed.The results showed that the SiO2@TPU porous material modified by SiO2 had distinct pore sizes and presented a three-dimensional hollow-out spheroidal hierarchical porous structure with high porosity and wide aperture distribution.The load of SiO2 formed a special infiltrating surface,reaching the super hydrophobic standard.The specific surface area was increased to 2 times of that before modification,the oil-water separation performance of SiO2@TPU material was better,and the adsorption rate was greatly improved.

SiO2TPUsaturated adsorption performanceoil water separation

林雨婷、陈康欣、李建宇、姜荣瀚、方萍

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绍兴文理学院化学化工学院 先进催化材料与功能分子合成平台 浙江绍兴 312000

SiO2 热塑性聚氨酯(TPU) 饱和吸附性能 油水分离

浙江省教育厅科研项目绍兴文理学院横向项目绍兴文理学院横向项目

Y202043125031/2022横010/2024横

2024

聚氨酯工业
中国聚氨酯工业协会 江苏省化工研究所有限公司

聚氨酯工业

CSTPCD
影响因子:0.507
ISSN:1005-1902
年,卷(期):2024.39(2)
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