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扩链系数对PUE力学性能的影响

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以聚丙二醇、对苯二异氰酸酯及扩链剂1,4-丁二醇为原料,采用预聚体法制备了一系列聚氨酯弹性体(PUE),研究了扩链系数对PUE力学性能、高低温性能等的影响.结果表明,在扩链系数0.95 至1.07 范围内,随着f值增加,材料的拉伸强度、撕裂强度和硬度先增后降.当f值为 0.98时,材料在常温下和100℃热态的力学性能表现均最好,f值的增加会降低材料的耐低温性能.
Effect of Chain Extension Coefficient on the Mechanical Properties of PUE
A series of polyurethane elastomer(PUE)samples were prepared by prepolymerization method using polyoxypropylene glycol(PPG),p-phenylene diisocyanate(PPDI)and chain extender 1,4-butanediol(BDO)as raw materials.The effects of chain extension coefficient(f value)on mechanical properties,thermal properties and low-temperature properties of PUE were studied.The results showed that the tensile strength,tear strength and hardness first increased and then decreased when f value increased from 0.95 to 1.07.When the f value was 0.98,the mechanical properties of the material were the best at room temperature and 100℃ high temperatures.The low-temperature resistance of the material would decreased with f value increasing.

polyurethane elastomerchain extension coefficientmechanical propertytemperature resistance

闫志浩、张维鹏、隋温楚、李闯、刘锦春

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青岛科技大学 橡塑材料与工程教育部重点实验室 山东青岛 266042

聚氨酯弹性体 扩链系数 力学性能 耐温性能

2024

聚氨酯工业
中国聚氨酯工业协会 江苏省化工研究所有限公司

聚氨酯工业

CSTPCD
影响因子:0.507
ISSN:1005-1902
年,卷(期):2024.39(3)