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含可逆键聚氨酯的研究进展

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含可逆键聚氨酯是体系中引入可逆键,在一定条件下该键断裂,聚氨酯具有新的结构和性能,撤销条件后又恢复其原有的结构和性能,且这种转化可重复进行的一类聚氨酯.综述了目前主要的含可逆键聚氨酯的合成路线及性能特点,对含有可逆非共价键及可逆共价键结构聚氨酯的研究进展进行了总结,并对含可逆键聚氨酯的应用前景进行了展望.
Research Progress of Polyurethane Containing Reversible Bonds
A type of polyurethane with reversible bonds in its molecular chain was called polyurethane containing reversible bonds.Under certain conditions,the reversible bonds would be broken,and polyurethane was granted new structures and properties.When the conditions were removed,the original structures and qualities of the polyurethane would be reverted,and this transformation could be repeated.In this paper,the current major synthetic routes and performance characteristics of polyurethane containing reversible bonds was reviewed,the research progress of polyurethane containing reversible non-covalent bonds and reversible covalent bonds structures was summarized,the application of polyurethane containing reversible bonds was prospected.

polyurethanereversible bondself-healingthermoreversible polyurethane

闫欣悦、张孝阿、王成忠

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北京化工大学材料科学与工程学院 碳纤维及功能高分子教育部重点实验室 北京 100029

聚氨酯 可逆键 自修复 热可逆聚氨酯

2024

聚氨酯工业
中国聚氨酯工业协会 江苏省化工研究所有限公司

聚氨酯工业

CSTPCD
影响因子:0.507
ISSN:1005-1902
年,卷(期):2024.39(4)