首页|氧化烧成下金属着色剂对黑釉呈色的影响

氧化烧成下金属着色剂对黑釉呈色的影响

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本文以中国历代黑釉瓷的特点为背景,研究了以石灰-碱釉为基础的釉料配方中MnO2和TiO2含量变化以及施釉厚度对黑釉呈色效果的影响.通过试验和反射光谱曲线分析,发现随着MnO2含量增加,黑釉呈现偏黄红色调,并且反射率呈先下降后上升的趋势.此趋势是由于高温下MnO2释放氧气,影响了Fe2+和Fe3+之间的平衡,适量添加MnO2有利于Fe3+离子迁移并消除黄绿色成分;TiO2含量也对黑釉发色效果产生显著影响,促使更多Fe2+转变为Fe3+,并产生黄色效果;混合添加MnO2和TiO2在黑釉呈色中起到重要作用,可改变反射特性使光线更多地被吸收.此外,施釉厚度同样对呈色有重要影响,过薄或过厚都会影响遮盖力.该研究对于丰富中国陶瓷文化、提升瓷器工艺水平以及传承和发展黑釉瓷艺术具有重要意义.
The Effect of Metal Colorants on the Color of Black Glaze under Oxidation Firing
Based on the characteristics of black glazed porcelain in China,this paper studies the changes in MnO2 and TiO2 content and the influence of glaze thickness on the color effect of black glaze in the glaze formula based on lime-alkali glaze.Through experiments and reflectance spectrum curve analysis,it is found that as the MnO2 content increases,the black glaze presents a yellowish-red tone,and the reflectivity first decreases and then increases.This trend is due to the release of oxygen by MnO2 at high temperatures,which affects the balance between Fe2+ and Fe3+.Adding an appropriate amount of MnO2 is beneficial to the migration of Fe3+ ions and eliminates the yellow-green color Ingredients;TiO2 content also has a significant impact on the color effect of black glaze,prompting more Fe2+ to transform into Fe3+,and producing a yellow effect;the mixed addition of MnO2 and TiO2 plays an important role in the color of black glaze,which can change the reflection characteristics so that more light is absorbed.In addition,the thickness of the glaze also has an important impact on the color.Too thin or too thick will affect the hiding power.This research is of great significance for enriching Chinese ceramic culture,improving the level of porcelain craftsmanship,and inheriting and developing the art of black-glazed porcelain.

Black GlazeGlaze FormulaReflectance Spectrum Curve

熊露、杨轩、俞星儿

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景德镇陶瓷大学

江西陶瓷文物遗存保护暨御窑研究协同创新中心

景德镇市融媒体中心

黑釉 釉料配方 反射光谱曲线

江西陶瓷文物遗存保护暨御窑研究协同创新中心项目江西省高等学校人文社会科学重点基地项目江西省研究生创新专项(2023)

JXYY2105JD20081YC2023-B243

2024

景德镇陶瓷
江西省景德镇陶瓷研究所

景德镇陶瓷

影响因子:0.047
ISSN:1006-9545
年,卷(期):2024.52(1)
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