首页|Synthesis and Crystal Structure of a Sandwiched Trinuclear Complex [Tl2(18-Crown-6)2Pt(CN)4]·2H2O

Synthesis and Crystal Structure of a Sandwiched Trinuclear Complex [Tl2(18-Crown-6)2Pt(CN)4]·2H2O

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The trinuclear complex bis(18-crown-6)thallium tetracyanoplatinate [Tl2(18-crown- 6)2Pt(CN)4]·2H2O was prepared and its structure was determined by X-ray diffraction analysis. The compound (C28H52N4O14PtTl2, Mr = 1272.57) crystallizes in monoclinic, space group P21/n with a = 10.5180(10), b = 8.6162(8), c = 21.118(2) (A), β = 92.577(2)°, V = 1911.9(3) (A)3, Z = 2, Dc = 2.211 g/cm3, F(000) = 1200, μ = 12.123 mm-1, R = 0.0181 and wR = 0.0427. The linearly arranged three metals are sandwiched by two 18-crown-6 molecules.

platinum, thallium, cyanide, 18-crown-6, crystal structure

LIU Feng-Hui、CHEN Wan-Zhi、WANG Da-Qi

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Department of Chemistry, Zhejiang University, Hangzhou 310028, China

Department of Chemistry and Chemical Engineering,Liaocheng University, Liaocheng 252059, China

浙江省自然科学基金

R405066

2006

结构化学
中国化学会 中国科学院福建物质结构研究所

结构化学

CSTPCDCSCD北大核心SCI
影响因子：0.44
ISSN：0254-5861
年,卷(期)：2006.25(6)
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