首页|An Organic-inorganic Hybrid Assembly Based on Novel Arsenatomolybdateand CuⅠ-Organic Units

An Organic-inorganic Hybrid Assembly Based on Novel Arsenatomolybdateand CuⅠ-Organic Units

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A novel organic-inorganic hybrid arsenatomolybdate based on infrequent [AsMo4O14(OH)2]3-unit,[CuⅠ(phen)2]3[AsMo4O14(OH)2]·3H2O (1,phen =1,10-phenanthroline),has been hydrothermally synthe-sized.This structure was determined by single-crystal X-ray diffraction analysis,and further characterized by elemental analysis,and IR and UV spectra.To the best of our knowledge,it is the first report of a novel arsenatomolybdate subunit [AsMo4O14(OH)2]3-.Photoluminescence of 1 is ascribed to π→π* emission of the aromatic rings derived from the phen ligand.

arsenatomolybdateorganic-inorganic hybridpolyoxometalate

LI Jie、TIAN Shu-Fang、LIU Yun、MA Peng-Tao

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Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China

This work was supported by the Foundation of Education Department of Henan Province

15A150037

2018

结构化学
中国化学会 中国科学院福建物质结构研究所

结构化学

CSCDSCI
影响因子：0.44
ISSN：0254-5861
年,卷(期)：2018.37(11)
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