结构化学2024,Vol.43Issue(4) :48-58.DOI:10.1016/j.cjsc.2024.100252

Templates for the synthesis of zeolites

Huimin Luan Qinming Wu Jianping Wu Xiangju Meng Feng-Shou Xiao
结构化学2024,Vol.43Issue(4) :48-58.DOI:10.1016/j.cjsc.2024.100252

Templates for the synthesis of zeolites

Huimin Luan 1Qinming Wu 2Jianping Wu 3Xiangju Meng 4Feng-Shou Xiao2
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作者信息

  • 1. College of Chemical and Biological Engineering,Zhejiang University,Hangzhou,310027,China;Kente Catalysts Inc.,Fengxi West Road,Modern Industrial Cluster,Xianju County,Zhejiang,317300,China
  • 2. College of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310027,China
  • 3. Kente Catalysts Inc.,Fengxi West Road,Modern Industrial Cluster,Xianju County,Zhejiang,317300,China
  • 4. Key Laboratory of Applied Chemistry of Zhejiang Province,Department of Chemistry,Zhejiang University,Hangzhou,310007,China
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Abstract

Though zeolites have been successfully synthesized for several decades,the roles of templates for zeolite synthesis are still not fully understood yet.Currently,many types of templates have been employed such as inorganic alkali metal ions,organic quaternary ammonium cations,organic amines,organic quaternary phosphonium cations,metal complexes and zeolite seeds,and the roles are mainly summarized into three aspects:structure-directing,space-filling and charge-balancing.In order to synthesize zeolites efficiently,the proposed principles to guide zeolite synthesis are the stabilization of energy between templates and zeolite framework,charge density mis-matching(CDM)and structure matching between zeolite frameworks and templates.The purpose of this review is to briefly summarize the progresses in recent years,clearly showing the roles of the templates for zeolite synthesis.

Key words

Zeolites/Templates/Zeolite synthesis/Zeolite structure

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出版年

2024
结构化学
中国化学会 中国科学院福建物质结构研究所

结构化学

CSCD
影响因子:0.44
ISSN:0254-5861
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