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MXene-based materials for separator modification of lithium-sulfur batteries

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Lithium-sulfur(Li-S)batteries are one of the promising energy storage systems.However,rapid capacity attenuation caused by shuttle effect of soluble polysulfides is a major challenge in practical application.The separator modification is one complementary countermeasure besides the construction of sulfur host materials in cathode.MXene is one type of outstanding candidates for promoting redox kinetics of sulfur species.Herein,recent advances of MXene-based materials as separator modifiers are summarized.The importance of high conductivity and catalytic effects in promoting catalytic conversion of polysulfides and suppressing shuttle effect of polysulfides has been highlighted,and the superiority of MXene for improving reversible capacity and cycling stability has been demonstrated.New strategies for the design of MXene-based separator modifiers are proposed to improve energy density and lifetime.The review provides new perspectives for future development of high-performance Li-S batteries.

MXeneLithium-sulfur batteriesSeparatorsShuttle effectsCatalysis

Fangling Cui、Zongjie Hu、Jiayu Huang、Xiaoju Li、Ruihu Wang

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Hebei Key Laboratory of Functional Polymer,School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin,300130,China

Natural Science Foundation of Hebei ProvinceState Key Laboratory of Structural Chemistry

B2023202053

2024

结构化学
中国化学会 中国科学院福建物质结构研究所

结构化学

影响因子:0.44
ISSN:0254-5861
年,卷(期):2024.43(7)