井冈山大学学报(自然科学版)2024,Vol.45Issue(3) :19-25.DOI:10.3969/j.issn.1674-8085.2024.03.004

MoS2/g-C3N4复合光催化剂的构建及其可见光催化性能研究

PREPARATION OF MOS2/G-C3N4 COMPOSITE PHOTOCATALYST AND ITS VISIBLE LIGHT CATALYTIC PERFORMANCE

廖文政 郑涛 陶珊珊 江昊 杨水金 杨赟
井冈山大学学报(自然科学版)2024,Vol.45Issue(3) :19-25.DOI:10.3969/j.issn.1674-8085.2024.03.004

MoS2/g-C3N4复合光催化剂的构建及其可见光催化性能研究

PREPARATION OF MOS2/G-C3N4 COMPOSITE PHOTOCATALYST AND ITS VISIBLE LIGHT CATALYTIC PERFORMANCE

廖文政 1郑涛 1陶珊珊 1江昊 1杨水金 2杨赟1
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作者信息

  • 1. 汉江师范学院化学与环境工程学院,湖北,十堰 442000
  • 2. 湖北师范大学化学化工学院,湖北,黄石 435002
  • 折叠

摘要

本研究通过水热合成法和超声法成功构建MoS2/g-C3N4复合型光催化剂.通过X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、红外光谱(IR)以及紫外-可见吸收光谱(UV-Vis)表征技术对复合型催化剂的物理化学特性进行分析.以光催化降解罗丹明B(RhB)为探针反应,探究可见光下不同质量比的MoS2/g-C3N4复合型光催化剂对RhB光催化降解性能的影响.实验结果表明,当MoS2负载量为30%,光催化降解80 min时,10mg/L的RhB溶液的降解率为96.7%.MoS2/g-C3N4复合催化剂相比于纯的g-C3N4,MoS2降解RhB的效果有显著地提高.光催化降解性能的提升归因于两半导体间MoS2和g-C3N4异质结界面构筑,有效地抑制光生电子(e-)和空穴(h+)的复合,从而提高复合型光催化剂MoS2/g-C3N4的光催化性能.

Abstract

In this study,hydrothermal synthesis and ultrasonic method were used to construct MoS2/g-C3N4 composite catalyst.The structure of the composite catalyst was characterized by X-ray powder diffraction(XRD),scanning electron microscopy(SEM),infrared spectroscopy(IR)and UV-Vis.The photocatalytic degradation of Rhodamine B(RhB)was investigated by using MoS2/g-C3N4 composite catalyst with different mass ratio as a probe.The results showed that the degradation rate of 10 mg/L RhB solution was 96.7%when MoS2 load was 30%and photocatalyzed for 80 min.Compared with pure g-C3N4,MoS2/g-C3N4 composite catalyst significantly improved the degradation effect of MoS2 on RhB.The improvement of photocatalytic degradation performance can be attributed to the fact that the heterojunction interface of MoS2 and g-C3N4 between the two semiconductors effectively inhibits the recombination of photogenerated electrons(e)and holes(h+).Finally,by reasoning the photocatalytic degradation mechanism of the composite photocatalyst,the charge transfer mechanism of MoS2/g-C3N4 is the same as that of type Ⅱ heterojunction,so it can be concluded that the composite belongs to type Ⅱheterojunction.

关键词

g-C3N4/纳米片/异质结构/光催化降解/水热法

Key words

g-C3N4/nanosheets/heterogeneous structure construction/photocatalytic degradation/hydrothermal method

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基金项目

国家自然科学基金面上项目(21673069)

国家级大学生创新创业训练计划项目(202416)

出版年

2024
井冈山大学学报(自然科学版)
井岗山大学

井冈山大学学报(自然科学版)

影响因子:0.298
ISSN:1674-8085
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