井冈山大学学报(自然科学版)2024,Vol.45Issue(6) :36-42.DOI:10.3969/j.issn.1674-8085.2024.06.006

聚酰亚胺/氧化铈有机无机杂化膜的制备研究

PREPARATION OF POLYIMIDE/CERIUM OXIDE ORGANIC-INORGANIC HYBRID MEMBRANE

冯发祥 苏诗 董桂林 师强 廖鑫怡 符瑞 韩润林
井冈山大学学报(自然科学版)2024,Vol.45Issue(6) :36-42.DOI:10.3969/j.issn.1674-8085.2024.06.006

聚酰亚胺/氧化铈有机无机杂化膜的制备研究

PREPARATION OF POLYIMIDE/CERIUM OXIDE ORGANIC-INORGANIC HYBRID MEMBRANE

冯发祥 1苏诗 1董桂林 1师强 1廖鑫怡 1符瑞 1韩润林1
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作者信息

  • 1. 井冈山大学化学化工学院,江西,吉安 343009
  • 折叠

摘要

实验以聚合物聚酰亚胺(PI)为膜材料,纳米氧化铈(CeO2)为无机添加剂,以水为凝胶浴试剂,采用浸没沉淀相转化法(NIPS)制备了 PI/CeO2有机无机杂化膜,并采用多胺对杂化膜进行化学交联处理.以染料刚果红和CuCl2溶液为目标污染物测试杂化膜的性能.实验结果表明,在CeO2含量为1.0wt%、交联剂浓度为1.273 g/L、交联时间为15 min、交联温度为80 ℃时,杂化膜在室温和0.3 MPa压力下对Cu2+的截留率为15.9%,对染料刚果红截留率为99.6%,膜通量为25.3 L/(m2-h).还进一步探究了在此条件下制备的杂化膜对其它染料的处理效果.最后,用扫描电子显微镜(SEM)分别观察PI膜和PI/CeO2有机无机杂化膜的表面结构.

Abstract

Polyimide(PI)/CeO2 hybrid membranes were prepared by immersion precipitation phase transformation(NIPS)using polymer PI as raw material and cerium oxide(CeO2)as inorganic additive material while water was used as coagulation agent.After that,the hybrid membrane was chemically cross-linked with amine,and the dye Congo red and CuCl2 solution were used as the target pollutants for interception treatment to test the performance of the hybrid membrane.The results showed that when CeO2 content was 1.0 wt%,crosslinking agent concentration was 1.273 g/L,crosslinking time was 15 min,crosslinking temperature was 80 ℃,the rejection rate of Cu2+and dye Congo red was 15.9%and 99.6%,respectively,at room temperature and pressure of 0.3 MPa.The membrane flux was 25.3 L/(m2.h).Moreover,the treatment effect of the hybrid membrane on other dyes was further investigated.Finally,the surface structures of PI membrane and PI/CeO2 organic-inorganic hybrid membrane were observed by scanning electron microscope(SEM).

关键词

浸没沉淀相转化法/聚酰亚胺膜/氧化铈/有机无机杂化膜/交联改性

Key words

immersion precipitation phase inversion method/polyimide membrane/cerium oxide/organic-inorganic hybrid membrane/cross-linking modification

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出版年

2024
井冈山大学学报(自然科学版)
井岗山大学

井冈山大学学报(自然科学版)

影响因子:0.298
ISSN:1674-8085
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