首页|Ti3AlC2对PcBN材料显微结构及性能的影响

Ti3AlC2对PcBN材料显微结构及性能的影响

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以不同质量分数的Ti3AlC2为结合剂,在5.5 GPa、1 450℃的条件下,制备整体式PcBN复合刀具材料,分析不同质量分数的Ti3AlC2对PcBN刀具材料的物相、显微结构及力学性能的影响.结果表明:Ti3AlC2在高温高压下会完全分解成TiC、Al-Ti合金,并与cBN反应生成AlN、TiB2和TiC0.7N0.3等物相;TiC、AlN、TiB2和TiC0.7N0.3均匀分布在cBN周围并与cBN紧密黏结在一起,从而提升PcBN的力学性能.当Ti3AlC2质量分数为25%时,PcBN的相对密度、抗弯强度、断裂韧性和磨耗比均达到最大值,分别为98.9%、592MPa、6.87MPa·m1/2和7 350;当Ti3AlC2质量分数为20%时,PcBN的显微硬度达到最大值4 786.7 HV.
Effect of Ti3AlC2 content on microstructure and properties of PcBN materials
The monolithic PcBN composite tool materials were prepared at 5.5 GPa and 1 450 ℃ with different con-tents of Ti3AlC2 as the binder phase.The effects of different mass fractions of Ti3AlC2 on the phase composition,micro-structure,and mechanical properties of PcBN tool materials were studied.The results show that Ti3AlC2 can decompose completely to form TiC and Al-Ti alloys under high temperature and high pressure,and reacts with cBN to form AlN,TiB2,and TiC0.7N0.3 phases.TiC,AlN,TiB2,and TiC0.7N0.3 are uniformly distributed around the cBN and tightly bonded to the cBN,thereby improving the mechanical properties of PcBN.When the mass fraction of Ti3AlC2 is 25%,the relat-ive density,bending strength,fracture toughness,and wear ratio of PcBN reach the maximum values,which are 98.9%,592 MPa,6.87 MPa.m1/2 and 7 350,respectively.When the mass fraction of Ti3AlC2 is 20%,the microhardness of PcBN reaches the maximum value of 4 786.7 HV.

PcBNTi3AlC2binderhigh temperature and high pressure(HTHP)mechanical properties

马金明、肖长江、陶宏均、张群飞、汤黎辉、曹剑锋、李远、周世杰、唐昱霖、陈亚超、栗正新

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河南工业大学材料科学与工程学院,郑州 450001

中原内配集团鼎锐科技有限公司,河南焦作 454750

精工锐意科技(河南)有限公司,郑州 450001

郑州沃德超硬材料有限公司,郑州 450001

郑州海科研磨工具有限公司,郑州 450001

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聚晶立方氮化硼 Ti3AlC2 结合剂 高温高压 力学性能

工信部科技高质量发展项目河南省科技重大专项河南省重点研发专项(2024)郑州市科技重大专项

203ZS202300052211002301002021KJZX0062

2024

金刚石与磨料磨具工程
郑州磨料磨具磨削研究所

金刚石与磨料磨具工程

CSTPCD北大核心
影响因子:0.354
ISSN:1006-852X
年,卷(期):2024.44(2)
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