首页|基于光致热弹光谱的硫化氢痕量气体高灵敏探测(特邀)

基于光致热弹光谱的硫化氢痕量气体高灵敏探测(特邀)

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光致热弹光谱(LITES)技术是近年来发展迅速的一种新颖痕量气体检测技术,该技术以体积小巧、成本低廉且无波长选择性的音叉式石英晶振替代成本高、探测波段窄的光电探测器作为光电换能器,通过探测激光与目标气体相互作用后光强的变化量实现目标气体浓度的反演。LITES技术具有探测灵敏度高、响应时间短、无波长选择性等优点。本文以下水道中的硫化氢气体为测量目标,开展了基于LITES技术的痕量气体探测系统的研究。以输出波长为1。582 μm的近红外连续波分布反馈单纵模二极管激光器作为激发光源,采用激光器波长调制和二次谐波探测技术,首先研究了激光波长调制深度对LITES系统产生的信号幅度的影响,而后详细研究了气体压强及环境压强对装置性能的影响。此外,为进一步提升装置探测灵敏度,有效光程长度为14。5 m的Herriott多通池被装配在激光器和作为光电探测器的音叉式石英晶振之间,从而使传感器在积分时间为300 ms时,获得4。87×10-7的最低探测极限,当积分时间延长至52 s时其探测灵敏度可达7。78×10-8。在完成装置各项参数优化之后开展了下水道中硫化氢气体的实测研究,结果显示,该系统完全可满足下水道臭气监测分析等领域的应用需求。
Detection of Hydrogen Sulfide Gas in Sewer Based on Light-Induced Thermoelastic Spectroscopy(Invited)
Light-induced thermoelastic spectroscopy(LITES)technology is a novel trace gas detection technology that has developed rapidly in recent years.The technology employs miniature,cost-effective,and wavelength-insensitive quartz tuning fork as substitutes for high-cost,narrow-bandwidth photodetectors in the field of optoelectronic transduction.The target gas concentration is achieved by detecting the variation in optical intensity resulting from the interaction between laser radiation and the target gas.LITES technology has the advantages of high detection sensitivity,short response time,and independence of excitation wavelength.In this paper,the research of trace gas detection system based on LITES technology is carried out with hydrogen sulfide(H2S)gas in sewers as the measurement target.A near-infrared distributed feedback laser with an output wavelength of 1.582 μm is employed as the excitation light source.The wavelength modulation spectroscopy and second harmonic detection techniques are utilized for trace gas concentration measurements.The impact of laser wavelength modulation depth on the signal amplitude generated by the LITES system is analyzed,and then the effect of operating pressure on the performance of the LITES system is also studied in detail.In addition,to further improve the detection sensitivity of the device,a Herriott multipass cell with an effective optical path length of 14.5 m is assembled between the laser and the quartz tuning fork.The sensor reached a minimum detection limit of~4.87×10-7 of H2S with an integration time of 300 ms.By extending the integration time to 52 s,the minimum limit can be reduced to~7.78×10-8.Using optimized parameters,on-site measurements of H2S in the sewer are conducted.The results indicate that the system is fully capable of meeting the application requirements in the fields of sewer odor monitoring and analysis.

light-induced thermoelastic spectroscopyquartz tuning forkhydrogen sulfidegas sensing

周美静、刘小利、崔茹悦、薛积禹、董磊、武红鹏

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山西大学激光光谱研究所量子光学与光量子器件国家重点实验室,山西 太原 030006

山西大学极端光学协同创新中心,山西 太原 030006

光致热弹光谱 音叉式石英晶振 硫化氢 气体传感

国家自然科学基金国家自然科学基金国家自然科学基金国家自然科学基金科技部国家外专局外专项目科技部重点研发计划

62122045620751196223501062175137G2023004005L2019YFE0118200

2024

激光与光电子学进展
中国科学院上海光学精密机械研究所

激光与光电子学进展

CSTPCD北大核心
影响因子:1.153
ISSN:1006-4125
年,卷(期):2024.61(3)
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