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超薄单晶硅光伏电池倒金字塔绒面设计及优化

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该研究构建具有倒金字塔绒面的前表面结构、双层减反膜、3 μm厚的单晶硅吸收层、指交叉背接触电极、氧化物钝化层的超薄光伏电池模型,利用时域有限差分法(FDTD)求解电磁波在半导体中传播的麦克斯韦方程组,进而得到场分布,优化倒金字塔绒面的倾斜度,实现了最佳44.65 mA⋅cm-2 理想短路电流密度.利用小信号交流扫描求解描述载流子运动规律的漂移扩散方程和描述静电势的泊松方程,使用粒子群优化算法优化指交叉背接触电极位置以及掺杂浓度,获得该模型的伏安特性曲线,计算得到该模型光电转化效率为23.03%.
Design and Optimization of Inverted Pyramid Suede for Ultrathin Monocrystalline Silicon Photovoltaic Cells
This study constructed an ultrathin photovoltaic cell model with an inverted pyramid velvet surface front structure,double-layer anti-reflection film,3 μm thick single-crystal silicon absorption layer,finger-crossed back contact electrode,and oxide passivation layer.The study first used the finite-difference time-domain(FDTD)method to solve the Maxwell equations of electromagnetic wave propagation in semiconductors,and it then obtained the field distribution.Next,the inclination of the inverted pyramid velvet surface was optimized and an optimal short-circuit current density of 44.65 mA⋅cm-2 was achieved.The study used small-signal alternating current scanning to solve the drift-diffusion and Poisson equations describing the carrier motion law and electrostatic potential,respectively.A particle swarm optimization algorithm was then employed to optimize the position and doping concentration of the finger-crossed back contact electrode.The model's volt-ampere characteristic curve was obtained,and its photoelectric conversion efficiency was calculated to be 23.03%.

photovoltaic cell efficiencysurface structurefinite-difference time-domain methodultrathin films

祁旭斌、向阳、杨阳

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河南理工大学物理与电子信息学院,河南 焦作 454003

光伏电池效率 表面结构 时域有限差分法 超薄薄膜

国家自然科学基金河南省科技攻关项目

61308029222102210247

2024

激光与光电子学进展
中国科学院上海光学精密机械研究所

激光与光电子学进展

CSTPCD北大核心
影响因子:1.153
ISSN:1006-4125
年,卷(期):2024.61(13)