江西化工2024,Vol.40Issue(2) :82-85.

碱金属掺杂对高温固相法制备的CaMoO4:Sm3+荧光粉发光性质的影响

Effect of Alkali Metal Doping on Luminescence Properties of CaMoO4:Sm3+Phosphors Prepared by High Temperature Solid-Phase Method

陈栋 狄世航 邓茜文 牛鹏英 吴宏越
江西化工2024,Vol.40Issue(2) :82-85.

碱金属掺杂对高温固相法制备的CaMoO4:Sm3+荧光粉发光性质的影响

Effect of Alkali Metal Doping on Luminescence Properties of CaMoO4:Sm3+Phosphors Prepared by High Temperature Solid-Phase Method

陈栋 1狄世航 1邓茜文 1牛鹏英 1吴宏越1
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作者信息

  • 1. 通化师范学院化学学院,吉林通化,134002
  • 折叠

摘要

在无机发光材料领域里,值得注意的是具有稳定化学及物理性质的优良材料钼酸钙.本次研究使用高温固相法制备一系列单一基质CaMoO4掺杂Sm3+的白光荧光粉,并使用XRD测试其物相结构,用激发和发射光谱测试发光性能.最终研究发现钼酸钙(CaMoO4)中Sm3+掺杂浓度为0.020时,荧光粉发光性能最强.当进一步掺杂碱金属作电荷补偿剂时,CaMoO4:0.020Sm3+的发光强度最优异,其中掺杂K+的荧光粉样品具有最大的发光强度,表明这种荧光粉在发光二极管照明方面具有深远而广阔的发展前景.

Abstract

In the field of inorganic luminescent materials,it is worth noting that calcium tungstate,an excellent material with stable chemistry and physical properties.In this study,a series of white phosphors doped with Sm3+with a single matrix CaMoO4 could be prepared using the high-temperature solid-phase method.Its phase structure is tested using XRD,and the luminescence performance can be tested by excitation and emission spectroscopy.The final study found that when the concentration of Sm3+doped in calcium molybdate(CaMoO4)was 0.020,the phosphor had the strongest luminescence performance,and when the alkali metal was further doped as a charge compensator,CaMoO4:0.020Sm3+had the best luminous intensity,and the K+-doped phosphor sample had the largest luminous intensity,indicating that this phosphor had unrevealed development prospects in terms of LED illumination.

关键词

无机发光材料/钼酸钙/Sm3+/高温固相法/碱金属

Key words

inorganic iuminescent materials/zinc molybdate/Sm3+/high temperature solid phase method/alkali metal

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基金项目

吉林省科技发展计划人才专项青年成长科技计划(2022)(20220508027RC)

通化师范学院大学生创新创业训练计划(202310202008)

出版年

2024
江西化工
江西化学化工学会 江西省化学工业研究所

江西化工

影响因子:0.272
ISSN:1008-3103
参考文献量19
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