首页|碱金属掺杂对高温固相法制备的CaMoO4:Sm3+荧光粉发光性质的影响

碱金属掺杂对高温固相法制备的CaMoO4:Sm3+荧光粉发光性质的影响

Effect of Alkali Metal Doping on Luminescence Properties of CaMoO4:Sm3+Phosphors Prepared by High Temperature Solid-Phase Method

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在无机发光材料领域里,值得注意的是具有稳定化学及物理性质的优良材料钼酸钙.本次研究使用高温固相法制备一系列单一基质CaMoO4掺杂Sm3+的白光荧光粉,并使用XRD测试其物相结构,用激发和发射光谱测试发光性能.最终研究发现钼酸钙(CaMoO4)中Sm3+掺杂浓度为0.020时,荧光粉发光性能最强.当进一步掺杂碱金属作电荷补偿剂时,CaMoO4:0.020Sm3+的发光强度最优异,其中掺杂K+的荧光粉样品具有最大的发光强度,表明这种荧光粉在发光二极管照明方面具有深远而广阔的发展前景.
In the field of inorganic luminescent materials,it is worth noting that calcium tungstate,an excellent material with stable chemistry and physical properties.In this study,a series of white phosphors doped with Sm3+with a single matrix CaMoO4 could be prepared using the high-temperature solid-phase method.Its phase structure is tested using XRD,and the luminescence performance can be tested by excitation and emission spectroscopy.The final study found that when the concentration of Sm3+doped in calcium molybdate(CaMoO4)was 0.020,the phosphor had the strongest luminescence performance,and when the alkali metal was further doped as a charge compensator,CaMoO4:0.020Sm3+had the best luminous intensity,and the K+-doped phosphor sample had the largest luminous intensity,indicating that this phosphor had unrevealed development prospects in terms of LED illumination.

inorganic iuminescent materialszinc molybdateSm3+high temperature solid phase methodalkali metal

陈栋、狄世航、邓茜文、牛鹏英、吴宏越

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通化师范学院化学学院,吉林通化,134002

无机发光材料 钼酸钙 Sm3+ 高温固相法 碱金属

吉林省科技发展计划人才专项青年成长科技计划(2022)通化师范学院大学生创新创业训练计划

20220508027RC202310202008

2024

江西化工
江西化学化工学会 江西省化学工业研究所

江西化工

影响因子:0.272
ISSN:1008-3103
年,卷(期):2024.40(2)
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