江西化工2024,Vol.40Issue(5) :42-45.

Bi2Se3/WSe2异质结构花球的制备与储钠性能研究

Preparation of Bi2Se3/WSe2 Heterojunction Flower-like Spheres and Study on Sodium Storage Performance

周梓楠
江西化工2024,Vol.40Issue(5) :42-45.

Bi2Se3/WSe2异质结构花球的制备与储钠性能研究

Preparation of Bi2Se3/WSe2 Heterojunction Flower-like Spheres and Study on Sodium Storage Performance

周梓楠1
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作者信息

  • 1. 宜春市锂电产业研究院,江西宜春,336000
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摘要

钠离子电池(SIBs)由于在成本、资源和安全性方面具有显著优势,被认为是一种有前途的锂离子电池替代方案.然而,它的实际应用受到容量低、倍率性能差和寿命短等问题的限制.本文采用一步水热法合成了Bi2Se3/WSe2花球异质结构,其中存在着丰富的孔隙.该结构可以在充放电过程中缓解体积效应,并且异质界面处的内建电场可以增强离子扩散反应,从而提高电化学性能.组装的Bi2Se3/WSe2半电池具有较高的初始库仑效率、循环稳定性和较强倍率能力.经过100次循环,钠离子电池(SIBs)在0.1 A·g-1下放电容量为402.6 mAh·g-1,在1 A·g-1下进行500次循环后,总量可达298.3 mAh·g-1,而在高倍率下(5 A·g-1),其容量仍能维持在259.1 mAh·g-1.

Abstract

Sodium-ion batteries(SIBs)are considered as a promising alternative to lithium-ion batteries due to their advantages in cost,resources,and safety.However,low capacity,poor rate capability,and short lifespan limits the practical application of SIBs.To address these issues,Bi2Se3/WSe2 flower-like heterostructures with abundant pore structure have been synthesized by a one-step hydrothermal method.This structure can mitigate the volume effect during charge and discharge process,and the built-in electric field at the heterojunction interface enhances ion diffusion reactions,thereby improving electrochemical performance.The assembled Bi2Se3/WSe2 half-cell exhibits high initial Coulombic efficiency,cycling stability,and rate capability.After 100 cycles,the discharge capacity at 0.1 A g-1 is 402.6 mAh·g-1,and after 500 cycles at 1 A·g-1,it reaches a specific capacity of 298.3 mAh·g-1.At high rates(5 A·g-1),the capacity remains high at 259.1 mAh·g-1.

关键词

钠离子电池/异质结构/金属硒化物

Key words

sodium-ion battery/heterostructure/metallic selenide

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出版年

2024
江西化工
江西化学化工学会 江西省化学工业研究所

江西化工

影响因子:0.272
ISSN:1008-3103
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