江西化工2024,Vol.40Issue(6) :72-76.

增塑剂705改性PLA/PBAT复合材料的制备及性能

Preparation and Properties of PLA/PBAT Composite Modified by Plasticizer 705

王小君 张青海 梁聪立 曾安然 陈婷 汪扬涛
江西化工2024,Vol.40Issue(6) :72-76.

增塑剂705改性PLA/PBAT复合材料的制备及性能

Preparation and Properties of PLA/PBAT Composite Modified by Plasticizer 705

王小君 1张青海 1梁聪立 2曾安然 1陈婷 1汪扬涛1
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作者信息

  • 1. 黎明职业大学新材料与鞋服工程学院,福建泉州,362000
  • 2. 皖羽<厦门>新材料科技有限公司,福建厦门,361100
  • 折叠

摘要

通过双螺杆挤出机熔融共混制备不同组分苯甲酸酯类增塑剂705改性聚乳酸/聚对苯二甲酸-乙二酸丁二醇酯复合材料,并通过熔体流动速率仪、差示扫描量热仪(DSC)、热重分析仪(TG)、微机控制电子万能试验机和摆锤冲击试验机研究其增塑剂705含量对复合材料的加工流动性能、热力学性能和力学性能的影响,分析表明了相比未添加增塑剂705的复合材料,当增塑剂705为15份时,熔体流动速率从15.12 g/10 min提高到33.27 g/10min,提高了 120.0%.增塑剂705含量增加会促进聚合物分子链段运动,使得复合材料的结晶温度、冷结晶温度和熔融温度降低,初始分解温度降低.2份增塑剂705适当提高了拉伸强度,而15份增塑剂705则使得复合材料的拉伸强度、弯曲模量和弯曲强度显著下降,缺口冲击强度达到 18.3 KJ/m2,提高了 325.6%.

Abstract

Different compositions of benzoate plasticizer 705 modified polylactic acid/poly(butylene adipate-co-terephthalate)composites were prepared by melt blending using a twin-screw extruder.The effects of plasticizer 705 content on the processing flow properties,thermodynamic properties,and mechanical properties of the composites were studied using a melt flow rate meter,differential scanning calorimeter,thermogravimetric analyzer,microcomputer-controlled electronic universal testing machine,and pendulum impact tester.The results showed that compared to the composite without plasticizer 705,the melt flow rate increased from 15.12 g/10min to 33.27 g/10min,an increase of 120.0%,when the plasticizer 705 content was 15 parts.Increasing the plasticizer 705 content promoted the movement of polymer molecular chains,resulting in lower crystallization temperature,cold crystallization temperature,and melting temperature of the composites,as well as a decrease in the initial decomposition temperature.Adding 2 parts of plasticizer 705 appropriately improved the tensile strength,while adding 15 parts of plasticizer 705 significantly reduced the tensile strength,flexural modulus,and flexural strength of the composites.And the notched impact strength reached 18.3 KJ/m2,an increase of 325.6%.

关键词

聚乳酸/聚对苯二甲酸-乙二酸丁二醇酯/增塑剂705/增塑

Key words

polylactic acid/poly(butylene adipate-co-terephthalate)/plasticizer 705/plasticization

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出版年

2024
江西化工
江西化学化工学会 江西省化学工业研究所

江西化工

影响因子:0.272
ISSN:1008-3103
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