首页|CO2间接矿化工业固废制备多晶型碳酸钙研究进展

CO2间接矿化工业固废制备多晶型碳酸钙研究进展

Preparation of various crystal forms of calcium carbonate from industrial solid waste by CO2 indirect mineralization

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CO2和工业固体废弃物的排放量逐年上升,威胁人类的生存和发展,世界各国迫切寻求降碳减排的解决路径.研究人员基于钙、镁元素与CO2反应生成稳定的碳酸盐反应,开发出一系列CO2矿化工艺,实现CO2的永久封存.为实现CO2的大规模封存和含钙固废的高值化利用,降低矿化成本,选取廉价易得的含钙工业固体废弃物为矿化原料,从多晶型微纳米碳酸钙的制备入手,总结了含钙工业固废浸取和CO2间接矿化的最新研究进展,介绍了含钙工业固废间接矿化常用的浸取剂,并着重分析了间接矿化制备微纳米碳酸钙时反应条件和晶型控制剂对碳酸钙晶型和形貌产生的影响,对其控制原理进行了解释说明,总结了CO2间接矿化含钙固废当前存在的技术难点,展望了未来的研究重点.国内外结果表明,调变温度、pH、搅拌速率以及CO2通气速率等矿化反应条件或添加晶型控制剂能有效控制碳酸钙的晶型、形貌和尺寸.利用含钙工业固体废弃物间接矿化CO2制备微纳米碳酸钙能够满足不同领域对碳酸钙的使用要求,能带来经济效益和环境效益,具有广阔的发展前景.
The emissions of CO2 and industrial solid waste are increasing year by year,posing a threat to human survival and development.Countries around the world are urgently seeking solutions to reduce carbon emissions.Researchers have developed a series of CO2 minerali-zation processes by reacting calcium and magnesium elements with CO2 to generate stable carbonates,achieving permanent CO2 storage.In order to achieve large-scale CO2 storage,high-value utilization of calcium containing solid waste,and reduce mineralization costs,inex-pensive and easily available calcium containing industrial solid waste was selected as mineralization raw materials.Started from the prepa-ration of polycrystalline micro nano calcium carbonate,the latest research progress on the leaching of calcium containing industrial solid waste and CO2 interstitial mineralization was summarized.The commonly used leaching agents for indirect mineralization of calcium contai-ning industrial solid waste were introduced,and the impact of reaction conditions and crystal form control agents on the crystal form and morphology of micro nano calcium carbonate during indirect mineralization preparation was analyzed.The control principle was under-stood and explained.Finally,the current technical difficulties and future research focus of indirect mineralization technology were summarized and discussed.The results indicate that adjusting the mineralization reaction conditions such as temperature,pH,stirring rate,and CO2 aeration rate,or adding crystal form control agents,can effectively control the crystal form,morphology,and size of calcium carbonate.The indirect min-eralization of CO2 from industrial solid waste containing calcium to prepare micro nano calcium carbonate can meet the requirements of different fields for the use of calcium carbonate,and can generate economic and environmental benefits,with broad development prospects.

CO2 mineralizationindustrial solid wastecrystal form regulationmorphological regulationcalcium carbonate

梅杰琼、陆诗建、任雪峰、康国俊、刘玲

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中国矿业大学江苏省煤基温室气体减排与资源化利用重点实验室 江苏徐州 221008

中国矿业大学碳中和研究院 江苏徐州 221116

中国矿业大学化工学院 江苏徐州 221116

矿化 工业固体废弃物 晶型调控 形貌调控 碳酸钙

宁波市科技计划江苏省碳达峰碳中和科技创新专项(2023)高校基本科研业务费项目科研基地建设专项

2022Z163BE20238522023KYJD1004

2024

洁净煤技术
煤炭科学研究总院 煤炭工业洁净煤工程技术研究中心

洁净煤技术

CSTPCD北大核心
影响因子:0.893
ISSN:1006-6772
年,卷(期):2024.30(3)
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