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煤粉掺氨空气分级燃烧排放特性及炉内过程烟气特性试验

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以往针对氨煤掺烧研究多集中在数值模拟及小型试验炉,大型试验炉上多为技术可行性的点工况试验.在一台50 kW自持燃烧下行试验炉中在不同工况下针对燃煤掺氨燃烧产物的排放和过程分布特性展开研究,重点分析了不同掺氨比例、燃尽风率及运行氧量的影响.为充分了解氨与煤燃烧过程中对NO生成的贡献,针对纯氨燃烧进行一系列试验.试验结果表明,空气分级燃烧可大幅降低燃煤掺氨燃烧NO的排放,掺氨比例为10%~90%时NO排放质量浓度在170-215 mg/m3,同纯煤燃烧NO排放质量浓度处于同一水平;最佳燃尽风比率维持在38%附近,继续增大燃尽风比率不会进一步降低NO排放,反而会导致燃烧不充分等负面影响.纯氨燃烧利用空气分级技术可以很好地控制出口 NO浓度,但纯氨燃烧稳定性远不及氨煤掺混燃烧,运行氧浓度较低时易出现氨逃逸现象.燃煤掺混氨燃烧既可解决氨燃烧困难、出口 NO排放浓度过高的问题,又可减少燃煤CO2排放,是一项极具潜力的技术路线.
Characteristics analysis of ammonia/coal co-firing with air staged combustion in one-dimensional self-sustained combustion experimental furnace
Previous studies on ammonia/coal co-firing have focused on numerical simulations and small-scale test furnaces,while large-scale test furnaces are mostly used for point-case tests of technical feasibility.In this paper,a detailed study of the emission and process distribution characteristics of ammonia/coal co-firing was carried out in a 50 kW one-dimensional self-sustained combustion experimental furnace under different operating conditions.In order to fully understand the contribution of ammonia and coal to NO production during the combustion process,a series of experimental studies were carried out for pure ammonia combustion.Air-staged combustion greatly re-duces NO emissions from ammonia/coal co-firing combustion.With ammonia co-firing ratios ranging from 10%to 90%,NO concentra-tions varie from 170 to 215 mg/m3,which are at the same level with pure coal combustion.The optimal burnout air ratio is maintained near 38%.Further increasing the burnout air ratio will not further reduce NO emissions,but will lead to negative effects such as inade-quate combustion.Pure ammonia combustion employing air-staged combustion technology can manage the exported NO concentration,but its stability is significantly worse than that of ammonia/coal co-firing,and ammonia is prone to escape when the oxygen concentration in the operation is low.Ammonia/coal co-firing may not only solve the problems of ammonia combustion difficulties and excessive NO emis-sions,but it can also minimize CO2 emissions from coal combustion,making it a very attractive technology route for future energy growth.

ammonia/coal co-firingair staged combustiondrop tube furnacepure ammonia combustionNO emission

汪鑫、韦耿、王勇、李维成、陈钧、范卫东

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上海交通大学机械与动力工程学院,上海 200240

清洁燃烧与烟气净化四川省重点试验室,四川成都 611731

东方电气集团东方锅炉股份有限公司,四川 自贡 643001

燃煤掺氨燃烧 空气分级 下行炉 纯氨燃烧 NO排放

国家重点研发计划

2023YFB4005705

2024

洁净煤技术
煤炭科学研究总院 煤炭工业洁净煤工程技术研究中心

洁净煤技术

CSTPCD北大核心
影响因子:0.893
ISSN:1006-6772
年,卷(期):2024.30(5)
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