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电站锅炉受热面高温氯腐蚀特性及防控

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随着我国双碳战略目标提出,电站锅炉向高参数方向发展.为研究新疆典型高氯煤在高参数锅炉焚烧过程中可能存在的腐蚀问题,探索防护措施,模拟了高参数下燃用高氯煤的锅炉气氛,对比了 Super 304、T92、C-HRA-5、TP347H和12Cr1MoV的抗氯腐蚀能力并研究腐蚀温度(600、650和700 ℃)对氯腐蚀特性的影响.同时探究不同氧化钇质量分数(0%、0.2%、0.4%、0.6%和0.8%)的In-conel 625涂层的抗氯腐蚀能力.结果表明:腐蚀温度对材料的抗氯腐蚀能力影响很大,当温度高于700 ℃ 时,Super 304、T92、C-HRA-5、TP347H 和 12Cr1MoV 均无法满足实际投产使用.在 650 ℃ 时,C-HRA-5和TP347H表现良好,其拟合的腐蚀增重曲线分别为:y2=312.371x,R2=0.96和y=1.927x,R2=0.94.Inconel 625涂层明显提高了 12Cr1MoV基体抗氯腐蚀能力.随着涂层中氧化钇含量增加,抗氯腐蚀效果呈先升高后降低趋势,添加0.4%氧化钇效果最好.
Investigations on the chloride corrosion characteristics and prevention on heating surface of power station boilers
With the proposal of the national dual carbon strategy,power station boilers tend to develop towards high parameters.In order to investigate the chlorine corrosion that may exist during the combustion of typical high-chlorine coal in Xinjiang in high-parameter boilers and to investigate its protective measures,the chlorine corrosion resistance of Super 304,T92,C-HRA-5,TP347H,and 12Cr1MoV were compared and the effect of corrosive temperatures(600,650,and 700℃)on the chlorine corrosion characteristics were investigated in the atmosphere of simulating burning high-chlorine coal in high-parameter boilers.The chlorine corrosion resistance of Inconel 625 coatings with different yttrium oxide contents(0%,0.2%,0.4%,0.6%and 0.8%)were also studied.The results show that the cor-rosion temperature has a great influence on the chlorine corrosion resistance of the material,and when the temperature is higher than 700 ℃,some of the materials will have great deformation,and Super 304,T92,C-HRA-5,TP347H and 12Cr1MoV are unable to meet the actual production use.At 650 ℃,C-HRA-5 and TP347H perform better with fitted corrosion weight gain curves of y2=312.371x,R2=0.96 and y=1.927x,R2=0.94.Inconel 625 coating significantly improves the 12CrlMoV substrate resistance to chloride corrosion.With the increase of yttrium oxide content in the coating,the anti-chlorine corrosion effect shows a trend of first increase and then de-crease,adding 0.4%yttrium oxide has the best effect.

power station boilershigh chlorine coalchlorine corrosionlaser claddinginconel 625

马道洋、李睿、张兰、坚永鑫、王毅斌、崔卫东、谭厚章、王学斌

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西安交通大学能源与动力工程学院,陕西西安 710049

河南省锅炉压力容器安全检测研究院,河南郑州 450016

西安交通大学材料科学与工程学院,陕西西安 710049

电站锅炉 高氯煤 氯腐蚀 激光熔覆 Inconel 625

国家重点研发计划青年科学家资助项目

2022YFB4100500

2024

洁净煤技术
煤炭科学研究总院 煤炭工业洁净煤工程技术研究中心

洁净煤技术

CSTPCD北大核心
影响因子:0.893
ISSN:1006-6772
年,卷(期):2024.30(6)