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催化滤袋脱硝性能及垃圾焚烧烟气的协同净化

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针对催化滤袋用于垃圾焚烧烟气脱酸、脱硝、除尘协同净化的技术思路,建立了协同净化实验系统,首先在烟气脱酸的前提下实验研究了关键因素对催化滤袋脱硝性能的影响,然后选取优化参数进行了协同净化实验.结果表明,在180~220 ℃的催化剂适用温度范围内的脱硝效率变化量约为15%,每提高10℃,氨逃逸体积分数下降约0.9 μL/L,150 ℃时脱硝效率和氨逃逸体积分数均严重偏离需求值;分别增加氨氮摩尔比0.1 mol/mol、烟气含水率5%、入口 NOx质量浓度100mg/m3、过滤风速0.1 m/min,脱硝效率的变化量分别约为4.1%、-2.6%、2.7%、-1.7%,氨逃逸体积分数变化量分别约为1.9、0.5、2.3、0.6 μL/L;脱酸脱硝协同净化时,在碱酸比1.1 mol/mol条件下,HC1脱除效率基本稳定在96%左右,SO2脱除效率达到97%以上且随氨氮摩尔比增加而略有增长趋势;氨氮摩尔比1 mol/mol以上时脱硝效率可以达到70%以上,氨氮摩尔比每增加0.1 mol/mol,脱硝效率增加约3.2%,氨逃逸体积分数增加约3.1 μL/L.
Denitration performance of catalytic filter bag and synergistic purification of waste incineration flue gas
Aiming at the technical idea of catalytic filter bag for synergistic purification of waste incineration flue gas deacidification,denitration and dedust,a synergistic purification experimental system was established.The effects of key factors on the denitration performance of catalytic filter bag were studied under the premise of waste incineration flue gas deacidification.Then the optimized parameters were selected to carry out the synergistic purification experiments.The results show that the denitration efficiency changes by about 15% within the applicable temperature range of 180-220 ℃.The ammonia escape decreases by about 0.9 μL/L for every 10 ℃increase.At 150 ℃,both denitration efficiency and ammonia escape concentration deviate seriously from the demand value.With the increase of ammonia nitrogen ratio 0.1 mol/mol,flue gas moisture content 5% ,inlet NOx concentration 100 mg/m3 and filtration velocity 0.1 m/min,the variation of denitration efficiency is about 4.1% ,-2.6% ,2.7% and-1.7% respectively,and the variation of ammonia escape concentration is about 1.9,0.5,2.3 and 0.6 μL/L respectively.In the synergistic purification experiments of deacidification and denitration,when the stoichiometric ratio of NaHCO3 to HC1+SO2 was 1.1 mol/mol,the removal efficiency of HC1 was basically stable at about 96% ,and the removal efficiency of SO2 reached more than 97% and increased slightly with the increase of NH3/NO.When the NH3/NO is above 1 mol/mol,the denitration efficiency can reach more than 70% .For every 0.1 mol/mol increase in NH3/NO,the denitration efficiency increases by about 3.2% ,and the ammonia escape concentration increases by about 3.1 μL/L.

waste incineration flue gascatalytic filter bagdenitrationdeacidificationsynergic purification

丁得龙、吴哲鹏、葛春亮、马如双、张屹覃、韦廷璠、胡达清、杨建国

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浙江天地环保科技股份有限公司,浙江 杭州 311121

浙江大学能源高效清洁利用全国重点实验室,浙江 杭州 310027

浙江大学嘉兴研究院,浙江嘉兴 314000

垃圾焚烧烟气 催化滤袋 脱硝 脱酸 协同净化

2024

洁净煤技术
煤炭科学研究总院 煤炭工业洁净煤工程技术研究中心

洁净煤技术

CSTPCD北大核心
影响因子:0.893
ISSN:1006-6772
年,卷(期):2024.30(11)