首页|芬顿高级氧化法处理电石法PVC聚合釜洗釜废水的试验研究及工程应用

芬顿高级氧化法处理电石法PVC聚合釜洗釜废水的试验研究及工程应用

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采用芬顿高级氧化法对电石法PVC聚合釜洗釜废水进行了小试试验.结果表明:在pH值为3.5,反应时间为60 min,H2O2:COD(质量比)=1:1,H2O2:Fe2+(摩尔比)=3:1的试验条件下,并兼顾COD去除率及运行成本的情况下,处理后的废水生物毒性得到大幅度降低,可生化性得到显著提升.后续采用以生化为主并引入其他保障处理工艺,最终出水COD可稳定在30mg/L以下,各项指标满足厂内循环水冷却水回用要求.
Experimental study and engineering application of Fenton advanced oxidation method for treating calcium carbide process PVC polymerization kettle washing wastewater
A small-scale experiment was conducted on treating washing wastewater of calcium carbide process PVC polymerization kettle by using Fenton advanced oxidation method.The results showed that under the experimental conditions of pH 3.5,reaction time of 60 minutes,mass ratio of H2O2 to COD of 1:1,and molar ratio of H2O2 to Fe2+ of 3:1,while considering COD removal rate and operating cost,the biological toxicity of the treated wastewater was significantly reduced,and the bio-degradability was significantly improved.Afterwards,biochemical treatment was adopted as the main method and other guarantee treatment processes were introduced.The final effluent COD could be stabi-lized below 30 mg/L,and all indicators met the requirements for reuse of circulating water and cooling water in the plant.

Fenton oxidation methodPVC polymerizerwaste waterbiodegradabilitybiological toxicityrecycling

刘政、贾金钢、许海滨

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北京铭泽源环境工程有限公司,北京 100020

内蒙古鄂尔多斯电力冶金集团股份有限公司氯碱化工分公司PVC公司,内蒙古 鄂尔多斯 016100

昊华宇航化工有限公司,河南 焦作 454000

芬顿氧化法 PVC聚合釜 废水 可生化性 生物毒性 回收利用

2024

聚氯乙烯
锦西化工研究院

聚氯乙烯

影响因子:0.214
ISSN:1009-7937
年,卷(期):2024.52(1)
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