精密成形工程2025,Vol.17Issue(1) :153-163.DOI:10.3969/j.issn.1674-6457.2025.01.018

高熵铝化物微叠层复合材料增-等材制备及组织性能研究

Additive-equal Material Fabrication and Microstructural Properties of High Entropy Aluminide Microlaminated Composites

覃红星 王宇 解蓓蓓 李伯君 范昊天 毕成龙 白舒乐
精密成形工程2025,Vol.17Issue(1) :153-163.DOI:10.3969/j.issn.1674-6457.2025.01.018

高熵铝化物微叠层复合材料增-等材制备及组织性能研究

Additive-equal Material Fabrication and Microstructural Properties of High Entropy Aluminide Microlaminated Composites

覃红星 1王宇 1解蓓蓓 1李伯君 1范昊天 1毕成龙 1白舒乐1
扫码查看

作者信息

  • 1. 中北大学材料科学与工程学院,太原 030051
  • 折叠

摘要

目的 研究高熵合金和铝增-等材复合制备材料的成形性能,以及制备的高熵铝化物微叠层复合材料的组织和力学性能.方法 首先研究了高熵合金和铝的复合材料增-等材制备各环节的成形性能,然后使用SEM、EDS、XRD分析了复合材料铝化物层的微观组织和生长动力学,最后从显微硬度、三点弯曲性能、断裂韧性、动态压缩强度的角度研究了复合材料的力学性能.结果 选区激光烧结成形的实物没有翘曲、弯曲等明显宏观缺陷,渗流铸造的复合材料孔洞较多,个别区域出现了较大尺寸的缺陷,真空热压烧结使复合材料结合紧实;复合材料的扩散行为是高熵合金扩散到Al层,Al基本不发生扩散;复合材料铝化物层的显微硬度高于铸造和SPS制备的高熵合金的显微硬度,随着靠近Al层,硬度呈降低现象,三点弯曲性能和断裂韧性随反应时间的延长而降低,动态压缩强度随反应时间的延长而提高.结论 高熵铝化物微叠层复合材料的增-等材复合制备材料成形性能良好;复合材料铝化物层的组织组成是Al3(Co,Cr,Fe,Ni),扩散层生长是晶内扩散和界面反应控制的混合型生长;铝化物层对复合材料性能的影响很大,其厚度增加,使复合材料三点弯曲性能和断裂韧性降低,动态压缩强度提高.

Abstract

The work aims to study the formability of high entropy alloy(HEA)and Al reinforced composites using the tech-nique of additive-equal material fabrication,as well as the microstructure and mechanical properties of the prepared high en-tropy aluminide microlaminated composites.Firstly,the formability of the composites in the preparation process of addi-tive-equal material fabrication was studied.Subsequently,the microstructure and growth kinetics of the composites'aluminide layer were analyzed by SEM,EDS,and XRD.Finally,the mechanical properties of the composites were investigated from the perspectives of microhardness,three-point bend,fracture toughness,and dynamic compressive strength.The physical objects fabricated by laser sintering melting exhibited no obvious macroscopic defects such as warping or bending,while the compos-ites fabricated by vacuum drift casting contained more voids,with some areas showing larger defects,and the aluminide com-posites fabricated by vacuum hot press sintering behaved very tightly.The diffusion behaviour of composites involved the diffu-sion of high entropy alloys into the Al layer,where Al underwent minimal diffusion.The microhardness of the aluminide layer was higher than that of the as-cast and spark plasma sintering prepared high entropy alloy.Near the Al layer,there was a de-crease in hardness.The three-point bend and fracture toughness decreased with increasing reaction time.The dynamic compres-sive strength increased with prolonged reaction time.High entropy aluminide microlaminated composites prepared by addi-tive-equal material fabrication has good formability.The microstructure composition of the aluminide layer of the composites is Al3(Co Cr Fe Ni),the aluminide diffusion layer shows a hybrid growth controlled by internal diffusion and interfacial reactions.The thickness of the aluminide layer has a significant impact on the performance of the composites.As the thickness increases,the three-point bend and fracture toughness of the composites decreases while the dynamic compressive strength increases.

关键词

增-等材制备/微叠层复合材料/高熵合金/动态压缩强度/断裂韧性

Key words

additive-equal material fabrication/microlaminated composites/high entropy alloy/dynamic compressive strength/fracture toughness

引用本文复制引用

出版年

2025
精密成形工程
中国兵器工业第五九研究所,国防科技工业精密塑性成形技术研究应用中心

精密成形工程

北大核心
影响因子:0.488
ISSN:1674-6457
段落导航相关论文