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高熵铝化物微叠层复合材料增-等材制备及组织性能研究

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目的 研究高熵合金和铝增-等材复合制备材料的成形性能,以及制备的高熵铝化物微叠层复合材料的组织和力学性能.方法 首先研究了高熵合金和铝的复合材料增-等材制备各环节的成形性能,然后使用SEM、EDS、XRD分析了复合材料铝化物层的微观组织和生长动力学,最后从显微硬度、三点弯曲性能、断裂韧性、动态压缩强度的角度研究了复合材料的力学性能.结果 选区激光烧结成形的实物没有翘曲、弯曲等明显宏观缺陷,渗流铸造的复合材料孔洞较多,个别区域出现了较大尺寸的缺陷,真空热压烧结使复合材料结合紧实;复合材料的扩散行为是高熵合金扩散到Al层,Al基本不发生扩散;复合材料铝化物层的显微硬度高于铸造和SPS制备的高熵合金的显微硬度,随着靠近Al层,硬度呈降低现象,三点弯曲性能和断裂韧性随反应时间的延长而降低,动态压缩强度随反应时间的延长而提高.结论 高熵铝化物微叠层复合材料的增-等材复合制备材料成形性能良好;复合材料铝化物层的组织组成是Al3(Co,Cr,Fe,Ni),扩散层生长是晶内扩散和界面反应控制的混合型生长;铝化物层对复合材料性能的影响很大,其厚度增加,使复合材料三点弯曲性能和断裂韧性降低,动态压缩强度提高.
Additive-equal Material Fabrication and Microstructural Properties of High Entropy Aluminide Microlaminated Composites
The work aims to study the formability of high entropy alloy(HEA)and Al reinforced composites using the tech-nique of additive-equal material fabrication,as well as the microstructure and mechanical properties of the prepared high en-tropy aluminide microlaminated composites.Firstly,the formability of the composites in the preparation process of addi-tive-equal material fabrication was studied.Subsequently,the microstructure and growth kinetics of the composites'aluminide layer were analyzed by SEM,EDS,and XRD.Finally,the mechanical properties of the composites were investigated from the perspectives of microhardness,three-point bend,fracture toughness,and dynamic compressive strength.The physical objects fabricated by laser sintering melting exhibited no obvious macroscopic defects such as warping or bending,while the compos-ites fabricated by vacuum drift casting contained more voids,with some areas showing larger defects,and the aluminide com-posites fabricated by vacuum hot press sintering behaved very tightly.The diffusion behaviour of composites involved the diffu-sion of high entropy alloys into the Al layer,where Al underwent minimal diffusion.The microhardness of the aluminide layer was higher than that of the as-cast and spark plasma sintering prepared high entropy alloy.Near the Al layer,there was a de-crease in hardness.The three-point bend and fracture toughness decreased with increasing reaction time.The dynamic compres-sive strength increased with prolonged reaction time.High entropy aluminide microlaminated composites prepared by addi-tive-equal material fabrication has good formability.The microstructure composition of the aluminide layer of the composites is Al3(Co Cr Fe Ni),the aluminide diffusion layer shows a hybrid growth controlled by internal diffusion and interfacial reactions.The thickness of the aluminide layer has a significant impact on the performance of the composites.As the thickness increases,the three-point bend and fracture toughness of the composites decreases while the dynamic compressive strength increases.

additive-equal material fabricationmicrolaminated compositeshigh entropy alloydynamic compressive strengthfracture toughness

覃红星、王宇、解蓓蓓、李伯君、范昊天、毕成龙、白舒乐

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中北大学材料科学与工程学院,太原 030051

增-等材制备 微叠层复合材料 高熵合金 动态压缩强度 断裂韧性

2025

精密成形工程
中国兵器工业第五九研究所,国防科技工业精密塑性成形技术研究应用中心

精密成形工程

北大核心
影响因子:0.488
ISSN:1674-6457
年,卷(期):2025.17(1)