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超高强度不锈钢不同海域的海洋腐蚀规律研究

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目的 研究Ferrium S53 钢和USS122G钢在青岛和三亚2 个海域大气和飞溅环境中的自然腐蚀规律.方法 采用腐蚀速率、点腐蚀深度、超景深三维显微分析及三维原子探针等方法,对Ferrium S53钢和USS122G钢在上述 2 个海域大气和飞溅区的腐蚀规律进行研究.结果 Ferrium S53 钢和USS122G钢在青岛和三亚 2个海域的大气和飞溅环境暴露 1 a后,2个钢种在青岛海域大气区和飞溅区的年平均腐蚀速率和平均点腐蚀深度均小于三亚海域.USS122G钢在青岛和三亚 2 个海域的大气和飞溅环境中的年平均腐蚀速率和平均点腐蚀深度均小于Ferrium S53 钢.结论 短期内,USS122G钢在上述2个海域具有比Ferrium S53 钢更好的耐蚀性能.Ferrium S53 钢与USS122G钢的主要强化体系不同,前者为M2C型碳化物,后者为Laves金属间化合物,M2C型碳化物中的Cr元素富集更为严重,析出相周围贫Cr区中的Cr元素含量更低,导致Ferrium S53 钢的耐腐蚀性能较差.
Marine Corrosion Behavior of Ultra-high Strength Stainless Steel in Different Marine Regions
The work aims to study the natural corrosion behavior of Ferrium S53 steel and USS122G steel in the atmos-pheric and splash zone environments of Qingdao and Sanya marine regions.The corrosion behavior of Ferrium S53 steel and USS122G steel in the atmospheric and splash zone environments of the two marine regions was investigated by methods such as corrosion rate measurement,pitting depth analysis,three-dimensional optical microscopy,and three-dimensional atom probe analysis.After 1 year of exposure in the atmospheric and splash zone environments of Qingdao and Sanya,the annual average corrosion rate and average pitting depth of the both steels in atmospheric and splash zone environments of Qingdao were lower than those in Sanya.The annual average corrosion rate and average pitting depth of USS122G steel were lower than those of Ferrium S53 steel in both atmospheric and splash zone environments of Qingdao and Sanya.In the short term,USS122G steel demonstrates better corrosion resistance than Ferrium S53 steel in the above-mentioned marine regions.The main strengthening mechanisms of Ferrium S53 steel and USS122G steel differ and the former is based on M2C carbides,while the latter is based on Laves phase intermetallic compounds.The Cr element is more heavily concentrated in the M2C carbides,leading to lower Cr content in the depletion zones around the precipitates,resulting in poorer corrosion resistance for Ferrium S53 steel.

ultra-high strength stainless steelmarine corrosionsplash zoneatmospheric environmentpitting corrosionstrengthening phase

王晓辉、刘振宝、梁剑雄、陈佳豪、杨志勇、赵文宇、田帅

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钢铁研究总院有限公司特殊钢研究院,北京 100081

哈尔滨工程大学烟台研究院,山东 烟台 264000

超高强度不锈钢 海洋腐蚀 飞溅区 大气环境 点蚀 强化相

2024

装备环境工程
中国兵器工业第五九研究所 国防科技工业自然环境试验研究中心

装备环境工程

CSTPCD
影响因子:0.985
ISSN:1672-9242
年,卷(期):2024.21(12)