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Eu(Ibu)3phen配合物的合成表征及发光性

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以药物布洛芬为第一配体,稀土离子Eu(Ⅲ)为中心离子,采用溶剂法合成了 Eu3+、布洛芬(Ibu)和邻菲罗啉(phen)的稀土-布洛芬药物配合物Eu(Ibu)3phen,采用元素分析、紫外光谱、红外光谱对配合物进行了初步结构表征,并研究了配合物的荧光性能.结果表明,该合成方法简单,Eu(Ibu)3phen产率较高,配合物Eu(Ibu)3phen的荧光发射光谱在612 nm出现Eu离子强特征荧光发射峰.该配合物有较好的发光性能,可作为安全环保的荧光材料.
Synthesis,Characterization and Luminescence of Eu(Ibu)3phen
Eu(Ibu)3phen was synthesized,with non-steroidal anti-inflammatory drug Ibuprofen as the first ligand,Phenanthroline as the second ligand and the rare earth ion Eu+as the central ion by solvent method.The structure of the complex was characterized by elemental analysis,UV spectroscopy,and in-frared spectroscopy,and the fluorescence properties of the complex were studied.The results indicate that ibuprofen can effectively serve as an antenna ligand,greatly sensitize luminescence of Eu3+,so the fluorescence emission spectra of the complex Eu(Ibu)3phen exhibit strong characteristic fluorescence e-mission peaks of europium ions at 589 nm and 612 nm.The complex has good luminescence perform-ance,so it can be used as a kind of environmentally friendly fluorescent material.

rare earth complexEuIbuprofenfluorescence property

王莹、沈景辉、胡丽娜、马冬云、史成阳、李炳寅

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佳木斯大学药学院,黑龙江佳木斯 154007

辽宁阜新高等专科学校化工系,辽宁阜新 123001

稀土配合物 Eu 布洛芬 荧光性质

2024

吉首大学学报(自然科学版)
吉首大学

吉首大学学报(自然科学版)

影响因子:0.451
ISSN:1007-2985
年,卷(期):2024.45(3)