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江苏某焦化厂周边土壤砷分布特征及影响因素

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为查清江苏某焦化厂周边土壤As污染的分布现状,探究不同土壤深度As富集与企业生产、地质背景等之间的联系,在焦化厂内布设447个样点,采集8.5 m以浅3个深度层位的土壤样品共1 313件;在焦化厂周边布设4条剖面18个样点,采集8.5 m以浅7个深度层位的土壤样品共119件.分析结果表明:研究区各层土壤均存在As超标情况,焦化厂内外均呈现As含量及其分布范围从表层到下层逐渐递增的规律,外部土壤中As超标率总体高于内部;周边浅表土壤As含量随离厂区距离增大而变小,且线性关系显著,浅表土壤As部分来源于焦化厂生产,迁移途径为大气降沉,且随着距离的增大影响程度变小,浅表受焦化厂影响较大;深部土壤中As主要来源于成土母质.总体上,研究区土壤As受地质背景影响显著,而焦化厂及其周边区域表层土壤As富集与焦化厂生产相关,As污染调查与治理时综合考虑焦化厂生产与地质背景更为科学.
Distribution characteristics and influencing factors of arsenic in the soil around a coking plant in Jiangsu Province
In order to find out the current distribution of soil arsenic pollution around a coking plant in Jiangsu Province,and explore the relationship between arsenic enrichment at different soil deeths and production and geological background,447 sample points were set up inside the plant to collect a total of 1 313 soil samples at 3 depths less than 8.5 m.A total of 119 soil samples at 7 depths less than 8.5 m were collected from 18 sample points from 4 profiles outside of the coking plant.The results showed that arsenic exceeded the standard in all soil layers in the study area,and its content and distribution range increased gradually from the surface to the deep inside and outside the coking plant.The overall As contamination rate in the soil outside the plant is higher than that within the plant.The content of arsenic in the shallow surface soil around the plant is positively correlated with the distance from the plant,and the linear relationship is significant.Part of the arsenic in the shallow surface soil comes from the coking plant production,and the migra-tion path is atmospheric deposition.With the increase of distance,the degree of influence is smaller.The shallow soil is more affected by the coking plant,while the deep soil arsenic mainly comes from the parent material.The overall soil arsenic in the study area is sig-nificantly affected by the geological background,and the concentration of arsenic in the surface soil of the coking plant and the sur-rounding area is related to the production of the coking plant.It is more scientific and reasonable to consider the production of the co-king plant and the geological background comprehensively in the As contamination investigation and treatment.

arsenic pollutionsoilgeologic backgroundcoking plant

金志鹏、金鹏、王安照、林强风

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江苏省地质勘查技术院,江苏南京 210049

As污染 土壤 地质背景 焦化厂

2024

地质学刊
江苏省地质调查研究院,江苏省地质学会,中国地质学会

地质学刊

影响因子:0.621
ISSN:1674-3636
年,卷(期):2024.48(3)