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镁离子电池的工作原理与关键材料

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镁离子电池具有原料丰富、成本低廉、环境友好以及高体积比容量等优点,近年来备受广泛研究.然而,充放电过程中缓慢的Mg2+扩散动力学性能、镁金属负极表面钝化层的形成以及电解液对空气敏感、腐蚀性强与电压窗口低等问题阻碍了其发展和实际应用.探索合适的电极材料以及与之兼容性好的电解液对镁离子电池的发展至关重要.简述了镁离子电池的工作原理,总结了镁离子电池正极、负极材料以及电解质的研究现状,并探讨了它们存在的问题以及相应的解决策略,旨在推动镁离子电池的进一步发展.
Working principle and key materials of Mg ion batteries
Magnesium ion batteries have been widely studied in recent years due to their advantages of abundant raw materials,low cost,environmental friendliness and high volumetric specific capacity.However,its development and practical application are limited by the slow diffusion kinetics of Mg2+,the formation of passivation layer on the sur-face of magnesium metal anode during cycling,and the sensitivity of electrolyte to air,strong corrosion and low volt age window.It is very important to explore suitable electrode materials and electrolytes with good compatibility.Herein,the working principle of magnesium ion batteries is described briefly.The research status of cathode and anode materials as well as electrolytes are summarized,and the existing problems and corresponding solutions are discussed elaborately in order to promote the further development of magnesium ion batteries.

magnesium ion batteriescathode materialsanode materialselectrolytesworking principle

谢清水、汪依依、夏丽、张一鸣、瞿佰华、王敬丰、周小元、彭栋梁

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厦门大学材料学院,福建厦门 361005

重庆大学材料科学与工程学院,重庆 400044

重庆大学物理学院,重庆 401331

镁离子电池 正极材料 负极材料 电解液 工作原理

国家重点研发计划项目

2023YFB3809500

2024

金属功能材料
中国钢研科技集团有限公司 中国金属学会功能材料分会

金属功能材料

CSTPCD
影响因子:0.527
ISSN:1005-8192
年,卷(期):2024.31(1)
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