首页|温度对3种不同材料铅酸蓄电池极板老化的影响

温度对3种不同材料铅酸蓄电池极板老化的影响

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铅酸蓄电池是变电站直流系统中最为常见的电源,在站用交流失电的情况下,能够及时向保护、测控等直流负荷供电.但阀控式铅酸蓄电池经较长时间运行后,较易出现极板老化的问题.研究温度变化对极板老化缺陷的影响.考虑温升条件的影响,制备了3组不同类型的蓄电池试样,分别使用铅钙板栅、铅锑板栅以及铅硒低板栅进行循环加速老化试验,测试每组试样在温升状态下的老化状态.经试验验证可知:在高温环境下(63 ℃)进行加速老化试验时,铅锑板栅和铅硒低板栅蓄电池的总容量明显低于铅钙板栅蓄电池,这表明这两组试样在高温条件下容易发生容量损失.同样,在该高温条件下,这两组试样的内阻与电流也明显高于铅钙板栅蓄电池,这说明它们在高温环境下的性能较差.内阻高会导致蓄电池充电和放电过程中能量损失增加,电流高可能会影响蓄电池的稳定性和寿命.此外,根据不同温度条件下(25、35和45 ℃)的测试结果,3组试样的放电时间逐渐加快,而电池容量则逐渐降低,这说明高温环境会加速蓄电池的老化过程,并导致电池容量损失.在3组蓄电池中,使用铅钙板栅的蓄电池极板在高温环境中使用寿命相对较长,老化速度最慢.
Influence of temperature on the aging of lead-acid battery plates made of three different materials
Lead acid batteries are the most common power source in the DC system of substations.In the event of AC power loss in the station,they can provide timely power to DC loads such as protection and measurement.Howev-er,valve regulated lead-acid batteries are prone to plate aging after prolonged operation.Study the effect of tempera-ture changes on the aging defects of electrode plates.Considering the influence of temperature rise conditions,three different types of battery samples were prepared,and cyclic accelerated aging tests were conducted using lead calci-um grid,lead antimony grid,and lead selenium low grid.Aging status of each group of samples under temperature rise conditions was tested.After experimental verification,it can be concluded that the total capacity of lead-antimo-ny grid and lead-selenium low grid batteries is significantly lower than that of lead-calcium grid batteries when sub-jected to accelerated aging tests in high temperature environments(63 ℃),indicating that these two groups of sam-ples are prone to capacity loss under high temperature conditions.Similarly,under the high temperature conditions,the internal resistance and current of these two groups of samples were significantly higher than those of lead-calci-um grid batteries,indicating their poor performance in high temperature environments.High internal resistance can lead to increased energy loss during battery charging and discharging,and high current may affect the stability and lifespan of the battery.In addition,according to the test results under different temperature conditions(25 ℃,35 ℃,and 45 ℃),the discharge time of the three sets of samples gradually accelerated,while the battery capacity gradually decreased.This indicates that the high-temperature environment will accelerate the aging process of the battery and lead to the loss of battery capacity.Among the three sets of batteries,the battery plates using lead-calci-um grids have a relatively long service life and the slowest aging rate in high-temperature environments.

lead-acid batteryinfluence of temperature riseplate aginglead calcium gridhigh temperature accel-erates agingbattery capacity

宫云茜、郁金星、李栋、王新刚、傅春明

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国网河北省电力有限公司电力科学研究院,河北石家庄 050021

山东电工电气集团数字科技有限公司,山东济南 250000

铅酸蓄电池 温升影响 极板老化 铅钙板栅 高温加速老化 电池容量

国家电网有限公司科技项目

TSS2022-16

2024

金属功能材料
中国钢研科技集团有限公司 中国金属学会功能材料分会

金属功能材料

CSTPCD
影响因子:0.527
ISSN:1005-8192
年,卷(期):2024.31(1)
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