首页|Pr基合金晶界扩散对烧结钕铁硼性能和结构的影响

Pr基合金晶界扩散对烧结钕铁硼性能和结构的影响

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通过丝网印刷涂敷技术,在烧结钕铁硼磁体表面分别涂敷了 Pr、Pr96Al4、Pr83Cu17、Pr80Co20涂层,并对其进行晶界扩散热处理.对比分析了扩散后磁体的磁性能、温度稳定性、相结构和微观结构.结果表明:扩散磁体的内禀矫顽力提高4 kOe以上,增幅超35%,剩磁降低0.3 kGs以内,降幅小于3%;扩散磁体的高温矫顽力明显提升,高温剩磁、剩磁温度系数和矫顽力温度系数基本不变,扩散Pr80Co20磁体的居里温度提升了 7.3 ℃;扩散源沿晶界扩散进入磁体内部,使得晶界富稀土相明显增多,有效地隔离了主相晶粒.
Effect of grain boundary diffusion of Pr-based alloy on the properties and structure of sintered NdFeB
Pr,Pr96Al4,Pr83Cu17 and Pr80 Co20 coatings were applied to the surface of sintered NdFeB magnets by screen printing technology,and the grain boundary diffusion heat treatment was carried out.The magnetic proper-ties,temperature stability,phase structure and microstructure of the diffused magnets were compared and analyzed.The results show that the intrinsic coercivity of the diffused magnets was increased by more than 4 kOe,an increase of more than 35%,and the remanence was reduced by less than 0.3 kGs,a decrease of less than 3%.The high-temperature coercivity of the diffused magnets were significantly improved,the high-temperature remanence,rema-nence temperature coefficient and coercivity temperature coefficient were basically unchanged,and the Curie temper-ature of the Pr80Co20 diffused magnet was increased by 7.3 ℃.The diffusion source diffuses into the magnet along the grain boundary,which significantly increases the number of RE-rich phase in the grain boundary,effectively iso-lating the main phase grains.

NdFeBPr-based alloygrain boundary diffusioncoercive forcemicrostructuretemperature stability

徐俊、查善顺、雷燕、何凡、刘友好、陈静武

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安徽大地熊新材料股份有限公司,稀土永磁材料国家重点实验室,安徽 合肥 231500

钕铁硼 Pr基合金 晶界扩散 矫顽力 微观结构 温度稳定性

2024

金属功能材料
中国钢研科技集团有限公司 中国金属学会功能材料分会

金属功能材料

CSTPCD
影响因子:0.527
ISSN:1005-8192
年,卷(期):2024.31(6)