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徐州市冬季PM2.5中碳质组分和水溶性离子特征分析

Characteristics of Carbon and Water-soluble Ions of PM2.5in Winter of Xuzhou City

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2018年1月12~22日在徐州市区进行大气颗粒物PM2.5和PM10的观测,分析PM2.5中碳组分和水溶性离子的含量,并利用气象资料分析重污染成因.结果表明:1月15日09:00到22日22:00徐州市新城区站连续182 h处于重度或严重污染,近地面交替出现的均压场、鞍型场和弱高压等不利气象条件是造成此次重污染的主因.重污染期间ρ(PM2.5)均值为195.5 μg/m3,ρ(PM10)均值为248.1 μg/m3,分别是非重污染期间的2.74和2.16倍;ρ(PM2.5)/ρ(PM10)为0.803,表明此次污染过程以细颗粒物为主.各组分ρ(OC)(17.0 μg/m3),ρ(EC)(7.62 μg/m3),ρ(SO42-)(31.0 μg/m3),ρ(NO3-)(62.3 μg/m3)和ρ(NH4+)(31.8 μg/m3)分别是非重污染期间的1.65,1.41,3.96,3.48和3.45倍,在PM2.5中占比分别是非重污染期间的0.62,0.53,1.49,1.32和1.30倍.重污染和非重污染期间,徐州市新城区OC,EC与PM2.5三者之间有明显的的相关性,ρ(OC)/ρ(EC)分别为2.11和2.29,表明有机碳存在明显的二次生成,ρ(NO3-)/ρ(SO42-)为2.26和2.16,表明徐州市新城区受机动车尾气影响较大.
The mass concentrations of the atmospheric particulates (PM2.5and PM10) and chemical components of PM2.5 were observed continuously from january 12 to 22, 2018, in Xuzhou urban. We analyzed the characteristic of mass concentration variations of PM2.5 and meteorological causes of heavy air pollutions process(HAPP) from meteorological data.Results showed that the meteorological conditions such as static,low wind speed and high humidity,caused severe or severe pollution of 182 hours between january 15(9:00 am)and 22(22:00 pm).During the HAPP,the average mass concentration of PM2.5 was 195.5 μg/m3 and of PM10 was 248.1 μg/m3,and ρ(PM2.5)/ρ(PM10) was 0.656~0.938,indicating that the HAPP was dominated by fine particles.The mass concentrations of OC,EC,SO42-,NO3- and NH4+ in PM2.5 were 17.0,7.62,31.0,62.3 and 31.8 μg/m3,respectively,with each component accounting for 8.70,3.90,15.8,31.9 and 16.3 percent of PM2.5,respectively,representing 0.62,0.53,1.49,1.32 and 1.30 times during the non-heavy air pollution period.During the period of heavy pollution and non-heavy pollution,there was a clear correlation between ρ(OC)and ρ(PM2.5),which was 2.11 and 2.29 respectively, the results indicating a significant secondary generation of organic carbon.ρ(OC)/ρ(EC)was 2.26 and 2.16 respectively,indicating that the new urban area was more affected by motor vehicle exhaust.So we should strengthen the control of vehicles in the new city of Xuzhou and surrounding areas,and reduce the emissions of nitrogen oxides and organic carbon.

PM2.5Carbonaceous compositionWater-soluble ionsSNA

李昌龙、王静怡、苗新慧、饶永才

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徐州市环境监测中心站,江苏 徐州221002

PM2.5 碳质组分 水溶性离子 SNA

2018

环境科技
徐州市环境监测中心站 江苏省环境科学研究院

环境科技

CSTPCD
影响因子:0.969
ISSN:1674-4829
年,卷(期):2018.31(2)
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