首页|固化改良对底泥中Cd迁移转化的影响研究

固化改良对底泥中Cd迁移转化的影响研究

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重金属污染底泥是疏浚底泥中较难处理的一种底泥,不仅需要改善其理化性质,还需要考虑重金属在底泥中的迁移转化.在石马河底泥中加入外源Cd2+并养护,同时加入固化材料和改良材料组合配方,研究在改善底泥理化性质的同时,固化材料和改良材料对Cd在底泥中迁移转化的影响.结果表明,底泥中加入外源Cd2+后,养护龄期达到7d时,底泥中Cd的形态基本稳定;加入以水泥为主的固化材料时,有助于底泥中Cd的形态从不稳定态向稳定态转化,且水泥的添加量越高,底泥浸出液中Cd的含量越低,通过对比分析得出,石马河底泥的固化配方宜为"40 kg/m3水泥 + 5 kg/m3 石灰 + 5 kg/m3 石膏";加入腐殖酸和稻草粉也有助于底泥中的Cd从不稳定态向稳定态转化,且稻草粉添加量宜为 200 g/kg,腐殖酸添加量宜为 5~10 g/kg.本研究成果可以为重金属污染底泥的资源化利用提供关键参数和科学依据.
Study on the Influence of Different Solidified Materials on the Migration and Transformation of Cd in Polluted Sediments
Heavy metal contaminated sediment is a kind of sediment difficult to be treated in dredging sediment.It is not only necessary to improve its mechanical and physical and chemical properties,but also to consider the migration and transformation of heavy metals in the sediment.Exogenous Cd2+ was added to the bottom mud of Shima River for curing,and the combination formula of different solidified materials and modified materials was added at the same time to study the migration and transformation of Cd in the bottom mud by solidified materials and modified materials while improving the physical and chemical properties of the bottom mud.The results showed that:After adding exogenous Cd2+ to the sediment,the transformation of Cd form in the sediment was basically stable when the curing period reached 7 days.When cement-based curing materials are added,it is helpful to transform the form of Cd in the sediment from unstable state to stable state,and the higher the amount of cement added,the lower the content of Cd in the sediment leaching solution.Through comparative analysis,it can be concluded that the curing formula of Shima River sediment should be"40 kg/m3 cement+5 kg/m3 lime + 5 kg/m3"gypsum.The addition of humic acid and straw meal can also help the conversion of Cd from unstable state to stable state in the sediment,and the addition amount of straw meal and humic acid should be 200 g/kg and 5~10 g/kg respectively.The results of this study can provide key parameters and scientific basis for the resource utilization of heavy metal contaminated sediment.

Solidified materialsCdPolluted sedimentsMigration and transformationLeaching solution

胡偲倢、谭艳忠、邱进生、傅利

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中国电建集团中南勘测设计研究院有限公司, 湖南 长沙 410014

固化材料 Cd 污染底泥 迁移转化 浸出液

湖南省流域水环境综合治理工程技术研究中心项目

2-2020-00372

2024

环境科技
徐州市环境监测中心站 江苏省环境科学研究院

环境科技

CSTPCD
影响因子:0.969
ISSN:1674-4829
年,卷(期):2024.37(1)
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