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高盐羟丙基甲基纤维素生产废水的预处理研究

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通过采用"Fe/C微电解+中和絮凝沉淀+电渗析"组合工艺分段处理高盐羟丙基甲基纤维素生产废水进行研究发现,"Fe/C微电解+中和絮凝沉淀"在优化条件下,COD去除率达35%,ρ(BOD5)/ρ(COD)由0.1提升至0.31,盐的质量分数仍高达3%,电导率为60.81 mS/cm.对沉淀后上清液进行电渗析,淡室盐分质量浓度和电导率分别可降至5 g/L,0.25 mS/cm以下,COD去除率达14.2%,出水满足生化处理要求,浓水盐分质量浓度可提升至150 g/L.该工艺实现了高盐废水的有效预处理,为达标排放提供了新的思路.
Research on Pretreatment of High Salt Hydroxypropyl Methylcellulose Production Waste water
The combination process of"Fe/C microelectrolysis+neutralization flocculation precipitation+electrodialysis"was used to treat high salt hydroxypropyl methylcellulose production wastewater in stages.Under the optimized conditions,the COD removal rate of"Fe/C microelectrolysis+neutralization flocculation precipitation"reached 35%,the BOD5/COD increased from 0.1 to 0.31,and the weight percentage of salt was still as high as 3%,with the electrical conductivity of 60.81 mS/cm.Electrodialysis of the supernatant after precipitation,the mass concentration of salt in the fresh room and the conductivity can be reduced to less than 5 g/L and 0.25 mS/cm respectively,the COD removal rate reaches 14.2%,the effluent meets the requirements of biochemical treatment,and the mass concentration of salt in the concentrated water can be increased to 150 g/L.The process realizes the effective pre-treatment of high salt wastewater,and provides a new way of thinking for the discharge to meet the standards.

MicroelectrolysisElectrodialysisHigh saltHydroxypropyl cellulose

王忠泉

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中煤科工集团杭州研究院有限公司,浙江 杭州 311201

微电解 电渗析 高盐 羟丙基纤维素

2024

环境科技
徐州市环境监测中心站 江苏省环境科学研究院

环境科技

CSTPCD
影响因子:0.969
ISSN:1674-4829
年,卷(期):2024.37(6)