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徐州市新城区大气VOCs污染特征及来源研究

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对徐州市新城区大气VOCs进行了连续在线观测,采用最大增量反应活性法对臭氧生成潜势进行了评估,识别了 VOCs关键活性物种,并利用正交矩阵因子模型对VOCs来源进行解析.结果表明,2023年4~11月徐州市新城区VOCs平均体积分数为22.14 × 10-9,组分占比呈现烷烃>卤代烃>烯炔烃>OVOCs>芳香烃的特征;OFP为100.06μg/m3,其中烯炔烃占比最大(40.36%),其次为芳香烃(32.84%);C2-C4烯烃和C7-C8芳香烃对OFP贡献较大.PMF模型识别出5个排放源,分别是工业源(34.7%)、机动车排放源(29.9%)、油气挥发源(19.7%)、溶剂使用源(11.3%)和天然源(4.4%).VOCs控制应以机动车排放源、溶剂使用源和油气挥发源为重点.
Pollution Characteristics and Sources Analysis of Ambient VOCs in New Urban Area of Xuzhou
The ambient volatile organic compounds were continuously monitored by an online monitoring system in Xincheng district of Xuzhou City.The maximum incremental reactivity(MIR)method was used to evaluate the ozone formation potential(OFP)of each species and identify the key active species.Positive matrix factorization(PMF)receptor model was used to analyze the potential sources of volatile organic compounds.The results showed that the average volume fraction of VOCs was 22.14×10-9 from April to November in 2023.The proportion of VOCs components was alkanes>halogenated hydrocarbons>alkenes(containing acetylene)>oxygenated compounds>aromatic hydrocarbons.The calculated OFPs were 100.06 μg/m3.Alkenes(containing acetylene)were the maximum contributors to OFPs,which accounted for 40.36%.Followed by aromatic hydrocarbons,which accounted for 32.84%.C2-C4 alkenes and C7-C8 aromatic hydrocarbons were the key active species to the OFP.Five emission sources were identified using PMF model,including industrial sources(34.7%),vehicle emissions(29.9%),oil and gas volatilization(19.7%),usage of solvents(11.3%)and plant emissions(4.4%).VOCs control should focus on vehicle emission sources,solvent use sources and oil and gas volatile sources.

Volatile organic compoundsCharacteristicsOzone formation potential(OFP)Positive matrix factorizationSource apportionment

李昌龙、吴萌萌

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江苏省徐州环境监测中心,江苏 徐州 221018

中国环境监测总站,北京 100012

挥发性有机物 污染特征 臭氧生成潜势 PMF模型 来源解析

2024

环境科技
徐州市环境监测中心站 江苏省环境科学研究院

环境科技

CSTPCD
影响因子:0.969
ISSN:1674-4829
年,卷(期):2024.37(6)