首页|基于微观界面作用力评价超滤膜不可逆污染的可行性

基于微观界面作用力评价超滤膜不可逆污染的可行性

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微观界面作用力被公认是评估膜污染机制的便捷有效手段,但微观界面作用力与不可逆膜污染之间的构效关系还缺乏研究。试验针对典型膜污染物和实际水体,采用拟合分析方法系统研究了"污染物-污染物""污染物-超滤(UF)膜"的微观界面作用力与总体膜污染(可逆污染和不可逆污染的叠加)、不可逆膜污染之间的相关性。结果表明,"污染物-UF膜"界面作用力与不可逆膜污染显著相关,相关系数均在 0。910 0 以上,最高可达 0。979 2,可用于评判超滤进水的不可逆膜污染累积潜能。"污染物-污染物"界面作用力与总体膜污染相关性更好,更适合评估进水总体膜污染潜能。研究结果为合理构建UF膜集成工艺提供了重要的依据。
Feasibility of Evaluation for Irreversible Fouling of UF Membrane Based on Micro-Interfacial Forces
Interfacial forces are recognized as an effective method to analyze the mechanism of membrane fouling.However,there are few reports on the causal relationship between micro-interfacial forces and irreversible membrane fouling.In the experiment,the interfacial forces between pollutants and between pollutants and ultrafiltration(UF)membrane were determined for typical membrane pollutants and actual water,and the correlation between them and total membrane fouling(i.e.,including reversible and irreversible membrane fouling)and irreversible membrane fouling was studied based on linear fitting analysis.The results suggested that,the interfacial force between pollutants and UF was significantly related to irreversible membrane fouling.The corresponding correlation coefficients were all above 0.910 0,and the highest was 0.979 2.Therefore,the interfacial force of"pollutants-UF"can be used to evaluate the irreversible membrane fouling potential of UF influent.The interfacial force between pollutants and pollutants had a better correlation with the total membrane fouling,which was more suitable for evaluating the total membrane fouling potential of UF influent.The research results provide an important reference for constructing a more reasonable membrane integration process of UF.

irreversible membrane foulingultrafiltration(UF)micro-interfacial forcemembrane fouling potentialcorrelation analysis

刘子豪、孟荣、崔运闯、魏伟

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国网河北省电力有限公司超高压分公司,河北石家庄 050000

艾科维尔<天津>科技有限公司,天津 300384

不可逆膜污染 超滤(UF) 微观界面作用力 膜污染潜能 相关性分析

国家电网有限公司科技项目

kj2022-055

2024

净水技术
上海市净水技术学会,上海市城乡建设和交通委员会科学技术委员会办公室

净水技术

CSTPCD
影响因子:0.643
ISSN:1009-0177
年,卷(期):2024.43(1)
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