净水技术2024,Vol.43Issue(2) :39-50,167.DOI:10.15890/j.cnki.jsjs.2024.02.005

工业水处理中的流化床Fenton工艺技术进展

Technical Progress of Fluidized Bed Fenton Process in Industrial Water Treatment

杨治国 方智煌 钱媛媛 杨雪晶
净水技术2024,Vol.43Issue(2) :39-50,167.DOI:10.15890/j.cnki.jsjs.2024.02.005

工业水处理中的流化床Fenton工艺技术进展

Technical Progress of Fluidized Bed Fenton Process in Industrial Water Treatment

杨治国 1方智煌 2钱媛媛 2杨雪晶1
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作者信息

  • 1. 华东理工大学上海工业水系统精益运营工程技术研究中心,上海 200237;华东理工大学机械与动力工程学院,上海 200237
  • 2. 华东理工大学上海工业水系统精益运营工程技术研究中心,上海 200237;麦王环境技术股份有限公司,上海 200082
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摘要

传统Fenton反应产生大量的铁泥,限制了该技术的推广应用.流化床Fenton是将传统Fenton和载体结晶相融合的一项高级氧化技术,在强化催化氧化废水处理效果的同时可以起到削减铁泥的作用.首先,文章从均相反应、非均相反应、载体结晶和技术机理 4 个方面,全面阐释了流化床Fenton的基本原理.继而,系统性地从载体特性、反应条件(Fenton试剂、pH、床层膨胀率和水基质)以及反应器结构等方面,全面分析了流化床Fenton工艺在废水处理中的关键影响因素.然后,回顾了近年来流化床Fenton工艺在难生物降解性工业废水等处理领域的工程化应用.最后,拓展性地从高效活性载体与耦合技术(光催化和膜生物处理)两方面详细地阐述了流化床Fenton技术优化,并对未来的研究方向和兴趣提出展望和思考.

Abstract

The main disadvantage of traditional Fenton process is that it may produce large amounts of sludge and limits the application of water treatment.Fluidized-bed Fenton process is an advanced oxidation technology which combines Fenton process and carrier crystallization.Fluidized-bed Fenton can not only enhance the effect of catalytic oxidation,but also reduce the iron sludge.In this review,the basic principle of fluidized bed Fenton is comprehensively introduced from four aspects:homogeneous reaction,heterogeneous reaction,carrier crystallization and technical mechanism.Secondly,the key influencing factor of fluidized-bed Fenton process in wastewater treatment are systematically introduced from the aspects of carrier characteristics,reaction conditions(Fenton reagent,pH value,bed expansion rate and water matrices)and reactor structure.Then,the engineering application of fluidized-bed Fenton process in recalcitrant industrial wastewater treatment in recent years are critically reviewed.Finally,the optimization of fluidized-bed Fenton process is expandingly expatiated from the perspective of high efficiency active carrier and coupling technology(photocatalysis and membrane biological treatment),and propose feasible survey direction and interest on future research.

关键词

流化床/工业水处理/结晶/载体/影响因素/工程化应用/优化

Key words

fluidized-bed/industrial water treatment/crystallization/carrier/influencing factor/engineering application/optimization

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基金项目

国家自然科学基金(21876049)

科技部重点研发计划(2019YFA0705800)

上海市上海工程技术研究中心项目(20DZ2250600)

出版年

2024
净水技术
上海市净水技术学会,上海市城乡建设和交通委员会科学技术委员会办公室

净水技术

CSTPCD
影响因子:0.643
ISSN:1009-0177
参考文献量11
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