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磺胺甲恶唑与纳米氧化锌对污泥活性的影响

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药物和个人护理用品(PPCPs)作为近年来被广泛认知的新污染物,引起了社会各界的关注.文章采用缺氧/好氧(AO)运行模式的序批式反应器(SBR),研究抗生素与纳米材料共存对活性污泥系统的影响,为促进污水处理系统稳定运行提供理论依据.结果表明,磺胺甲恶唑(SMZ)与ZnO纳米颗粒(NPs)共存时,SBR反应器中混合液悬浮固体浓度(MLSS)与混合液挥发性悬浮固体浓度(MLVSS)/MLSS分别降低 17.67%以及 9.73%,污泥活性受到抑制.进一步研究表明,相比于空白组,两者共存时污泥出水中溶解性微生物产物(SMP)的多糖以及蛋白质含量增加 39.0%以及 63.3%,并且使聚磷菌生物除磷能力降低,进而影响处理效能.最后,通过活性氧(ROS)、三磷酸腺苷(ATP)以及乳酸脱氢酶(LDH)指标研究了微生物活性的变化.结果显示,SMZ与ZnO NPs共存会对ROS、ATP以及LDH产生显著抑制效应.
Effect of Sulfamethoxazole and ZnO NPs on Sludge Activity
PPCPs as emerging pollutants that have been widely recognized in recent years,have attracted the attention of all sectors of society.This study used a sequencing batch reactor(SBR)in anoxic/aerobic(AO)operation mode to investigate the effects of coexistence of antibiotics and nanomaterials on activated sludge systems and to provide a theoretical basis for promoting the stable operation of wastewater treatment systems.Results showed that the coexistence of sulfamethoxazole(SMZ)and ZnO nano-particles(NPs)reduced the MLSS and MLVSS/MLSS in the SBR reactor by 17.67%and 9.73%,respectively,and the sludge activity was suppressed.Further studies showed that compared to the blank group,the polysaccharide and protein content of the SMP in coexistence system in the sludge effluent increased by 39.0%and 63.3%and reduced the biological phosphorus removal capacity of the phosphorus-polymerising bacteria,thus affecting the treatment efficiency.Finally,this study investigated the variations in microbial activity through reactive oxygen species(ROS),adenosine triphosphate(ATP)and lactate dehydrogenase(LDH)indices.Results showed that the coexistence of SMZ and ZnO NPs produced significant inhibitory effects on ROS,ATP and LDH.

sulfamethoxazole(SMZ)ZnOnano-particles(NPs)sludge activitybiological phosphorus removalmicrobial activity

路云霞、李超、钱唐健、卜现亭、王超越

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南京市生态环境保护科学研究院,江苏南京 210013

河海大学环境学院,江苏南京 210019

磺胺甲恶唑(SMZ) ZnO 纳米颗粒(NPs) 污泥活性 生物除磷 微生物活性

2024

净水技术
上海市净水技术学会,上海市城乡建设和交通委员会科学技术委员会办公室

净水技术

CSTPCD
影响因子:0.643
ISSN:1009-0177
年,卷(期):2024.43(2)
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