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污水中阴离子表面活性剂的影响及去除

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文章系统研究了应用较为广泛的阴离子表面活性剂——十二烷基苯磺酸钠(SDBS)对生物池中污染物(氨氮、总磷、硝态氮)的去除影响以及不同混凝剂[聚合氯化铝(PAC)、硫酸铝(AS)、聚合硫酸铁(PFS)、三氯化铁(FeCl3)]对SDBS去除效能和最佳投加位点的选择。试验结果表明,氨氮和总磷的去除率随着SDBS浓度的增加会明显降低,SDBS对以上两种污染物的去除有显著的抑制作用,而SDBS对硝态氮的去除基本无影响。通过进一步试验得出,FeCl3作为混凝剂可以更有效去除SDBS,当FeCl3与SDBS在最佳质量配比(3∶1)时,SDBS的去除率可达到78。3%。在提升泵站、初沉池出口、外回流液中投加FeCl3对SDBS皆有明显的去除效果,但在初沉池出水中投加时SDBS的去除效果最佳。
Influence and Removal of Anionic Surfactants in Waste water
This paper systematically studied the effect of sodium dodecyl benzene sulfonate(SDBS),a widely used anionic surfactant,on the removal of pollutants[ammonia nitrogen,total phosphorus(TP),and nitrate nitrogen]in biological ponds,as well as the selection of different coagulants[polyaluminum chloride(PAC),aluminum sulfate(AS),polyferric sulfate(PFS),and ferric chloride(FeCl3)]for SDBS removal efficiency and optimal dosing sites.The experimental results showed that the removal rates of ammonia nitrogen and TP significantly decreased with the increase of SDBS concentration.SDBS had a significant inhibitory effect on the removal of the above two pollutants,while SDBS had little effect on the removal of nitrate nitrogen.Through further experiments,it was found that FeCl3 as a coagulant could more effectively remove SDBS.When the optimal mass ratio of FeCl3 to SDBS was 3:1,the removal rate of SDBS could reach 78.3%.The addition of FeCl3 to the lift pump station,the outlet of the primary sedimentation tank,and the external reflux had a significant removal effect on SDBS,but the optimal removal efficiency was achieved when adding FeCl3 to the outlet water of the primary sedimentation tank.

wastewater treatmentanionic surfactantbiochemical poolcoagulation and sedimentationcoagulant

黄伟、韩晓宇、陈江荣、姚富森、黎方铃、陈默、蒙晓琴、李晓林

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重庆三峡水土排水有限公司,重庆 401122

重庆市农业生态与资源保护站,重庆 401120

西南大学化学化工学院,重庆 400715

污水处理 阴离子表面活性剂 生化池 混凝沉淀法 混凝剂

2024

净水技术
上海市净水技术学会,上海市城乡建设和交通委员会科学技术委员会办公室

净水技术

CSTPCD
影响因子:0.643
ISSN:1009-0177
年,卷(期):2024.43(6)