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华南地区污水处理厂污泥中微塑料的典型赋存特征

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在污水处理过程中大部分城市污废水中的微塑料污染物被转移到剩余污泥中,阐明其分布特性,对于明晰城市微塑料排放和环境影响,具有重要的意义。研究以位于广州市不同行政区的3座污水处理厂为调查对象,跟踪采集其污水和污泥样品,分离其中所含微塑料污染物,通过显微拉曼分析其特性,绘制污水处理厂微塑料污染图谱。3座污水处理厂对污水中微塑料的去除率>95%。这些微塑料被转移到剩余污泥中。干污泥中,微塑料浓度为(19。6±8。4)、(39。5±15。6)个/g和(15。9±4。8)个/g。污泥中微塑料的形状可分为球状、不规则块状、纤维状和薄膜状。球状和纤维状来自生活污水,不规则块状则有一部分来自工业源。所检测到的微塑料中,尺寸为1~100 µm的占比达到80%~90%。而且,纤维状微塑料与较大尺寸(50~100 µm)微塑料之间存在一定的关联性。在所检测到的微塑料中,透明和白色占主要部分,其数量比例为60%~90%。在材质方面,聚乙烯和聚丙烯微塑料占比为60%~80%,而其他十几种材质的微塑料则占比较少。总之,污水处理厂的微塑料与其污水来源关系密切相关。
Typical Occurrence Characteristics of Microplastics in Sludge of WWTP in Southern China
Most of the microplastic pollutants in urban wastewater are migrated to the remaining sludge during the wastewater treatment process.Elucidating their distribution characteristics is of great significance for clarifying the emission and environmental impact of microplastics from urban wastewater sources.Herein,three wastewater treatment plants(WWTPs)located in different administrative districts of Guangzhou were selected,and their wastewater and sludge samples were tracked and collected.The three WWTPs contributed a removal rate of over 95%for microplastics in wastewater.These microplastics were migrated to the remaining sludge.In the dry sludge,microplastic concentrations were(19.6±8.4),(39.5±15.6)g-1 and(15.9±4.8)g-1.The shapes of microplastics in sludge included spherical,irregular block,fibrous and film shapes.The spherical and fibrous shapes originated from domestic wastewater,while part of the irregular blocks originated from industrial sources.Among the detected microplastics,80%~90%had sizes in the range of 1μm to 100 μm.Moreover,there was a certain correlation between fibrous microplastics and larger size(50~100 µm)microplastics.Among the detected microplastics,transparent and white materials accounted for the main parts,with their quantity proportion ranging from 60%to 90%.In terms of materials,polyethylene and polypropylene microplastics accounted from 60%to 80%,while microplastics of more than a dozen other materials account for relatively small amounts.In summary,microplastics in WWTPs are closely related to their wastewater sources.

microplastics(MP)wastewater treatmentRaman spectrummigration and transformationnovel pollutant

邓海洋、廖芷安琪、刘沛文、区华丽、曹耀宇、欧桦瑟

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中节能建设工程设计院有限公司,四川成都 610052

暨南大学环境与气候学院,广东 广州 511443

暨南大学物理与光电工程学院,广东 广州 510632

微塑料 污水处理 拉曼光谱 迁移转化 新污染物

2024

净水技术
上海市净水技术学会,上海市城乡建设和交通委员会科学技术委员会办公室

净水技术

CSTPCD
影响因子:0.643
ISSN:1009-0177
年,卷(期):2024.43(12)