净水技术2024,Vol.43Issue(12) :195-204.DOI:10.15890/j.cnki.jsjs.2024.12.022

前置O3/H2O2-生物炭流化床在水厂提标工程中的设计应用

Design and Application of Pre-O3/H2O2-Biochar Fluidized Bed Processes in WTP Upgrading

姚恒军 彭锦玉 李振邦 李晓民 付成胜 王新伟 王全勇
净水技术2024,Vol.43Issue(12) :195-204.DOI:10.15890/j.cnki.jsjs.2024.12.022

前置O3/H2O2-生物炭流化床在水厂提标工程中的设计应用

Design and Application of Pre-O3/H2O2-Biochar Fluidized Bed Processes in WTP Upgrading

姚恒军 1彭锦玉 2李振邦 3李晓民 3付成胜 3王新伟 3王全勇3
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作者信息

  • 1. 潍坊市市政公用事业服务中心,山东潍坊 261046
  • 2. 山东华城工程技术有限公司,山东济南 250101;山东大学环境科学与工程学院,山东济南 250100
  • 3. 山东华城工程技术有限公司,山东济南 250101
  • 折叠

摘要

山东L水厂设计规模为12万m3/d,提标改造前,水厂以常规处理工艺为主,并采用投加高锰酸钾和粉末活性炭来去除原水中的2-甲基异莰醇(2-MIB)和土臭素(GSM),但仅可应对2-MIB质量浓度不高于80 ng/L的情形.为满足新版《生活饮用水卫生标准》(GB 5749-2022)、提高供水水质,建成了前置臭氧/双氧水(O3/H2O2)-生物炭流化床工艺,创新性地将深度处理工艺置于常规处理工艺之前以去除嗅味物质,并降低有机物、藻类等对常规处理工艺的影响,提升整体工艺处理效率.提标改造后,在原水2-MIB质量浓度不高于600 ng/L时,滤池出水2-MIB质量浓度降至5 ng/L以下,高锰酸盐指数、浑浊度、颗粒数等水质指标亦有大幅度降低.同时,水厂停止投加粉末活性炭与高锰酸钾,减少了聚合氯化铝(PAC)与次氯酸钠投加量,并关停了气浮工艺,吨水制水成本降低了 0.129-0.171元,为同类水厂提标改造提供了工程经验和案例支撑.

Abstract

Shandong L water treatment plant(WTP)is designed with a capacity of 120 000 m3/d.Before upgrading and renovating,the WTP primarily uses conventional treatment processes and adds potassium permanganate and powderes activated carbon to remove 2-methylisoborneol(2-MIB)and geosmin(GSM)from raw water,but this can only cope with 2-MIB mass concentrations not exceeding 80 ng/L.To meet the requirements of the new Standards for Drinking Water Quality(GB 5749-2022)and enhance water supply quality,a pre-ozone/hydrogen peroxide(O3/H2O2)-biochar fluidized bed process is constructed.This innovative approach involves integrating advanced treatment processes prior to conventional treatment to remove odorous compounds and minimize the adverse effects of organic matter and algae on standard treatment,thus improving overall treatment efficiency.After upgrading and renovating,when the 2-MIB mass concentration in the raw water does not exceed 600 ng/L,the mass concentration of 2-MIB in the filtered water decreases to below 5 ng/L.Other water quality indices,including the permanganate index,turbidity and particle count,also showes substantial improvement.Additionally,the WTP discontinues the use of powdered activated carbon and potassium permanganate,reduces the dosages of PAC and sodium hypochlorite,and decommissiones the flotation process.As a result,the water production cost per cubic meter is lowered by 0.129 yuan to 0.171 yuan.This case study provides valuable engineering experience and serves as a reference for similar upgrading in WTP.

关键词

前置高级氧化/臭氧/双氧水/生物炭流化床/2-甲基异莰醇/土臭素

Key words

pre-advanced oxidation/ozone/hydrogen peroxide/biochar fluidized bed/2-methylisoborneol(2-MIB)/geosmin(GSM)

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出版年

2024
净水技术
上海市净水技术学会,上海市城乡建设和交通委员会科学技术委员会办公室

净水技术

CSTPCD
影响因子:0.643
ISSN:1009-0177
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