基于HSE评价的反应路径综合方法
Reaction path synthesis based on HSE evaluation
焦巍 1孙晓岩 2夏力 2项曙光2
作者信息
- 1. 青岛科技大学炼油化工高新技术研究所,山东,青岛,266042;青岛大学师范学院,山东,青岛,266071
- 2. 青岛科技大学炼油化工高新技术研究所,山东,青岛,266042
- 折叠
摘要
为在过程早期获取健康、安全和环境(Health,Safety and Environment,HSE)较好的化学反应路径,提出了考虑HSE的反应路径综合策略,通过原料筛选规则、本质HSE评价和非线性优化综合得到优良的反应路径.结合本质安全原理和物质属性,制定了原料筛选规则,消除危害性物质;通过本质HSE评价得到各原料物质的指标值;以HSE指标为目标函数,建立NLP反应路径综合模型,求解得到优良的反应路径组合.将该方法应用于氯乙烯反应路径综合实例,结果表明在反应路径综合同时有效考虑安全、环境和健康因素,以获得较优的反应路径,为过程设计早期决策提供定量依据.
Abstract
Aimed to obtain chemical reaction path with benign HSE impact during early phase of chemical process,the strategy of reaction path synthesis considering HSE factors is proposed.The benign reaction path will be obtained through material screening rules,inherent HSE evaluation and NLP synthesis.Based on inherent safety principles and material nature,material screening rules are formed to eliminate the substance with extreme hazardous characteristic.The HSE value of every material is obtained by inherent HSE evaluation.Treating the HSE index as the objective function,the NLP model for reaction path synthesis is established.The stoichiometric coefficient of benign reaction path is acquired by solving the model in MATLAB.Finally by analyzing the application of reaction path synthesis for VCM production,the result shows that HSE factors can be considered during reaction path synthesis.The chemical reacdon path obtained provides quantified support for process decision-making in early stage of process research.
关键词
反应路径综合/HSE/NLP模型/氯乙烯过程Key words
reaction path synthesis/HSE/NLP model/VCM process引用本文复制引用
基金项目
国家自然科学基金(20976085)
山东省自然科学基金(ZR2011BL011)
青岛市科技计划基础研究项目(09-01-03-05-JCH)
出版年
2013
NETL
NSTL
维普
万方数据