首页|氧化对铜硫矿物浮选影响的研究现状

氧化对铜硫矿物浮选影响的研究现状

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大多数铜硫矿物表面易氧化,而氧化会对矿物浮选行为及药剂在矿物表面的吸附产生重要影响.目前,关于氧化对铜硫矿物浮选的影响,研究者开展了大量相关研究并取得了显著成果.从铜硫矿物表面氧化影响因素出发,重点分析了溶液性质、矿物晶格缺陷等因素对铜硫矿物表面氧化的影响机理.针对氧化后铜硫矿物浮选回收难度增加的原因进行了分析,一方面,氧化后铜硫矿物表面溶解产生的金属离子增加,会使铜硫矿物表面相互影响严重,造成铜硫矿物难以浮选分离;另一方面,铜硫矿物表面氧化产生的强亲水性的金属氧化物及氢氧化物则会严重减弱捕收剂的有效吸附,使铜硫矿物可浮性降低.基于此,从铜硫矿物表面氧化层脱落方法和氧化后铜硫矿物表面调控方法两方面论述了氧化后铜硫矿物浮选强化措施及其机理.最后,针对氧化后铜硫矿物浮选强化措施提出了相关建议,以期为实现氧化后铜硫矿物高效浮选回收提供借鉴.
Research Status on the Effect of Oxidation on Flotation of Copper-Sulfide Minerals
The surfaces of most copper-sulfide minerals are easily oxidized,which have a significant effect on the flotation of the minerals and the adsorption of reagents on the surface of minerals.At present,researchers have conducted extensive re-search on the effect of oxidation on the flotation of copper-sulfide minerals,and have obtained remarkable achievements.Based on the factors affecting the surface oxidation of copper-sulfide minerals,this paper focuses on analyzing factors such as solution properties,mineral lattice defects on the surface oxidation of copper-sulfide minerals.The difficulty of the flotation of copper-sulfide minerals after oxidized increased and the reasons are analyzed.On one hand,the metal ions increased generated from the oxidation and dissolution,which will cause serious interaction effect of copper-sulfide minerals,thus making it difficult to realize the flotation separation of copper-sulfide minerals.One the other hand,the strong hydrophilic metal oxides and hydrox-ides generated from the surface oxidation of copper-sulfide minerals will seriously weaken the effective adsorption of collectors,resulting in a decrease in the floatability of copper-sulfide minerals.Based on this,the flotation strengthening measurements and mechanism of copper-sulfide minerals after oxidized are discussed from two aspects:the shedding method of the oxidation layer and the surface regulation method of copper-sulfide minerals after oxidized.At last,the relevant suggestions were proposed a-bout the flotation strengthening measurements of oxidized copper-sulfide minerals.This could provide reference for achieving the effective flotation recovery of oxidized copper-sulfide minerals.

copper sulfide mineralsflotationoxidation mechanismreagents adsorptionstrengthening measurements

薛季玮、刘启鸿、刘童、田宇、卜显忠、宛鹤、任大伟、李唐博

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西安建筑科技大学资源工程学院,陕西西安 710055

铜硫矿物 浮选 氧化机理 药剂吸附 强化措施

国家自然科学基金国家自然科学基金国家自然科学基金国家级大学生创新创业训练计划

521042665207420652374278202210703013

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(2)
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