金属矿山2024,Issue(2) :276-280.DOI:10.19614/j.cnki.jsks.202402034

镍渣对粉煤灰基地质聚合物收缩性能的影响

Influences of Nickel Slag Addition on Shrinkage Behavior of Fly Ash-based Geopolymer

齐道正 王炳监 陈登 李莉
金属矿山2024,Issue(2) :276-280.DOI:10.19614/j.cnki.jsks.202402034

镍渣对粉煤灰基地质聚合物收缩性能的影响

Influences of Nickel Slag Addition on Shrinkage Behavior of Fly Ash-based Geopolymer

齐道正 1王炳监 1陈登 2李莉1
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作者信息

  • 1. 盐城工业职业技术学院建筑工程学院,江苏盐城 224005
  • 2. 苏州科技大学土木工程学院,江苏苏州 215011
  • 折叠

摘要

镍渣是镍冶炼过程中排出的工业固废,以镍渣为原料制备地质聚合物,既提高了地质聚合物的绿色环保属性,更有助于促进镍铁合金工业的可持续发展.向粉煤灰基地质聚合物中掺入镍渣,并考察镍渣掺量对硬化体收缩性能的影响.结果表明,镍渣掺量为25%时不仅提高了地质聚合物的抗压强度,同时有助于降低自收缩和干燥收缩.镍渣反应活性较低,掺入粉煤灰基地质聚合物中会减缓碱激发反应进程,进而降低硬化体自收缩.另一方面,镍渣颗粒在硬化体中发挥微骨料作用,掺入后有助于降低地质聚合物孔隙率,既提高了硬化体的抗压强度,同时抑制干燥过程中的水分蒸发并降低了干燥收缩.

Abstract

Nickel slag is the industrial solid waste discharged during the nickel production.Using nickel slag as a raw ma-terial to prepare geopolymers not only reduces the carbon footprint of geopolymers,but also promotes the sustainable develop-ment of the nickel-iron alloy industry.In this paper,nickel slag wasincorporated into the fly ash-based geopolymers,and the in-fluences of the slag addition on the shrinkage behavior of the binders were investigated.The results showed that the 25%nickel slag addition not only improved the compressive strengths of the geopolymers,but alsoreduced the autogenous shrinkage and dr-ying shrinkage ratios.Nickel slag exhibitedrelatively lower reactivity than fly ash.The addition into fly ash-based geopolymers slowed down the kinetics of alkali-induced reaction,and consequently mitigated the self-shrinkage of the binders.On the other hand,nickel slag particles played themicro-aggregate role in the binders.The pore structure of geopolymers was compacted.It not only enhanced the compressive strengths of the binders,but also restricted the water evaporation during the drying process and consequently reduced the drying shrinkage.

关键词

地质聚合物/镍渣/收缩/抗压强度/孔结构

Key words

geopolymer/nickel slag/shrinkage/compressive strength/pore structure

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基金项目

江苏省高等学校"青蓝工程"培养对象资助项目(培养人:齐道正)()

江苏省高职院校青年教师企业实践培训项目(2020QYSJ183)

江苏省产学研合作项目(BY2022175)

出版年

2024
金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
参考文献量16
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