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低硅铁尾矿制备轻质泡沫混凝土试验研究

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为解决低硅铁尾矿堆存量大、利用困难等问题,以杨家湾尾矿库内低硅铁尾矿为矿物掺和料,水泥为胶凝材料,Al粉为发泡剂,制备轻质泡沫混凝土,并考察了水泥掺量、水料比、发泡剂Al粉掺量、激发剂CaO掺量等因素对泡沫混凝土性能的影响.结果表明:在铁尾矿掺量 55%、Al粉掺量 0.14%、CaO掺量 5%、聚丙烯纤维掺量 0.3%、稳泡剂掺量 0.25%、水料比 0.55 的条件下,经 20±1℃恒温恒湿养护 28 d,可制备出抗压强度 1.84 MPa、干密度 768.61 kg/m3、比强度 2.394×10-3 Nm/kg的轻质泡沫混凝土,综合性能良好,符合JG/T 266-2011《泡沫混凝土》之A08 干密度等级、C1 强度等级要求.机理分析表明:孔隙率的过度提高会破坏制品内部的孔隙结构,对制品强度造成负面影响;铁尾矿的添加有助于混匀料浆,促进Ca(OH)2 的生成,为料浆进一步创造碱性环境,促进钙矾石、C—S—H凝胶等水化产物的生成,其与铁尾矿的交织分布会支撑起孔隙结构,改善力学结构,使泡沫混凝土即使在较低密度下仍表现出较好的力学性能.
Experimental Study on Preparation of Lightweight Foamed Concrete by Low Silicon Iron Tailings
In order to solve the problem of large stock and difficult utilization of low-silicon iron tailings,lightweight foamed concrete was prepared by using low-silicon iron tailings from Yangjiawan tailings reservoir as mineral admixtures,ce-ment as cementitious material and Al powder as foaming agent.The effects of cement dosage,water-to-material ratio,foaming a-gent Al powder dosage and activator CaO dosage on the performance of foamed concrete were investigated.The results showed that under the condition of iron tailings dosage of 55%,Al powder dosage of 0.14%,CaO dosage of 5%,polypropylene fiber dosage of 0.3%,foam stabilizer dosage of 0.25%and water-to-material ratio of 0.55,the lightweight foamed concrete with compressive strength of 1.84 MPa,dry density of 768.61 kg/m3 and specific strength of 2.394×10-3 Nm/kg could be prepared after curing 28 days of constant temperature and humidity at 20±1℃.The comprehensive performance was good,which met the requirements of A08 dry density grade and C1 strength grade of JG/T 266-2011 Foamed concrete.The mechanism analysis showed that the excessive increase of porosity would destroy the pore structure inside the products and had a negative impact on the strength of the products.The addition of iron tailings helped to mix the slurry,promoted the formation of Ca(OH)2,further created an alkaline environment for the slurry,and promoted the formation of hydration products such as ettringite and C—S—H gel.The interlaced distribution of these products and iron tailings would support the pore structure and improve the mechani-cal structure,so that the foamed concrete still showed good mechanical properties even at a low density.

low-silicon iron tailingsfoamed concretemechanismAl powderspecific strength

韩厚胜、李育彪、潘梦真、陈坤、张媛、顾雲翔、薛璐韬、蹇守卫

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武汉理工大学资源与环境工程学院,湖北 武汉 430070

矿物资源加工与环境湖北省重点实验室,湖北 武汉 430070

硅酸盐建筑材料国家重点实验室,湖北 武汉 430070

低硅铁尾矿 泡沫混凝土 机理 Al粉 比强度

湖北省重点研发计划项目

2020BCA007

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(4)
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