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沉积型锂矿的成矿特征及锂赋存状态研究进展

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随着新能源汽车和锂电池的快速发展,锂资源已成为许多国家的重要战略资源.然而,全球锂资源分布不均,中国当前锂资源的对外依存度高达 75%,但待开发的沉积型锂矿较丰富,其锂的成矿特征和赋存状态制约着其分离提取和高效开发利用.通过梳理现阶段沉积型锂矿的研究成果,介绍了全球锂资源的主要类型及其特点,分析了沉积型锂矿的形成地质背景和时空分布特征,认为沉积型锂矿已成为全球新型锂资源的重要类型,具有储量大、分布广、开采成本低等优势而表现出巨大的开发价值和广阔的利用前景.总结出 3 大特征:① 沉积型锂矿通常分为火山岩黏土型、碳酸盐黏土型/伴生型和贾达尔型,其主要分布在北美洲、南美洲、欧洲和亚洲等地区,成矿时代多为新生代,部分与铝土矿和煤系伴生的沉积型锂矿形成于古生代或中生代.② 火山岩黏土型锂矿多形成于封闭的湖相沉积盆地,成矿物质主要来源于火山岩浆活动;贾达尔型锂矿中锂的主要来源为不同时期的河流沉积物和火山喷发物质;碳酸盐黏土型/伴生型锂矿中锂主要来源于沉积环境,其富集过程通常与风化沉积作用有关.③ 火山岩黏土型锂矿中锂主要赋存在锂皂石、伊利石和锂蒙脱石中.碳酸盐黏土型/伴生型锂资源中矿物组成不同,锂的赋存状态主要有 3 种:① 赋存在锂绿泥石的层间氢氧化物层中;② 赋存在伊利石结构八面体或假六方环中;③ 赋存在高岭石结构八面体中.贾达尔型锂矿中锂主要存在于矿物贾达尔石的晶体结构中.最后,展望了中国沉积型锂资源的研究方向和开发利用前景,以期为中国锂资源的地质勘察高效开发提供支撑.
Research Progress on the Metallogenic Characteristics of Sedimentary Lithium Deposits and the Occurrence State of Lithium
With the rapid development of new energy vehicles and lithium batteries,lithium resources have become im-portant strategic resource for many countries.However,the distribution of global lithium resources is uneven,and China's lithi-um resource dependence on foreign countries is as high as 75%.There are abundant sedimentary lithium deposits to be devel-oped,the mineralization characteristics and occurrence state of lithium restricts its separation,extraction and efficient develop-ment and utilization.This paper introduces the main types of global lithium resources and their characteristics,analyzes the temporal and spatial distribution characteristics and the formation of geological background of sedimentary lithium deposits,and argues that sedimentary lithium deposits have become an important type of new lithium resources in the world.Due to it has the advantages of large reserves,wide distribution and low exploitation cost,it shows great development value and broad utilization prospect.By summarizing and reviewing the research results of sedimentary lithium deposits at the present stage,three major characteristics are summarized:① sedimentary lithium deposits mainly divided into three types:volcanic clay type,carbonate clay type/associated type and jadar type.They are mainly distributed in North America,South America,Europe and Asia.Its metallogenic age is mostly in the Cenozoic era,and part of the sedimentary lithium ore associated with bauxite and coal system was formed in the Paleozoic or Mesozoic era.② Volcanic clay lithium deposits are mostly formed in the closed lake-phase sedi-mentary basin,the mineralization material mainly comes from volcanic magmatic activities.The main sources of lithium in Ja-dar-type lithium deposits are river sediments and volcanic eruptions in different periods.The lithium in carbonate clay-type/as-sociated lithium deposit mainly originates from the sedimentary environment,and its enrichment process is mainly related to weathering and sedimentation.③ In volcanic clay type lithium deposit,lithium mainly occurs in Li-smectite,hectorite and il-lite;The mineral composition of carbonate clay type/associated type lithium resources is different,and there are three types of lithium occurrence states:① occurs in the lithium chlorite interlayer hydroxide layer;② occurs in the illite structure octahedral or pseudohexagonal ring;③ occurs in the kaolinite structure octahedral.In Jadal type lithium deposits,lithium mainly exists in the crystal structure of the independent mineral Jadarite.Finally,this paper provides prospects for the research direction and exploitation prospects of sedimentary lithium resources in China,which provide support for geological exploration and efficient development of lithium resources in China.

sedimentary lithium depositclay mineralslithium contentoccurrence state

程宏飞、周轩平

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长安大学地球科学与资源学院,陕西 西安 710054

沉积型锂矿 黏土矿物 锂含量 赋存状态

国家自然科学基金面上项目中央高校基本科研业务费专项长安大学项目

42172043300102263301

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(5)
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