首页|基于宏-微观测试方法的铁尾矿-沥青界面黏附研究

基于宏-微观测试方法的铁尾矿-沥青界面黏附研究

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铁尾矿作为一种新材料加入沥青会产生新的界面,其与沥青的界面黏附性直接影响沥青混合料的路用性能.为揭示铁尾矿-沥青界面黏附的作用机理,通过X射线荧光光谱仪、X射线衍射仪、扫描电子显微镜等对铁尾矿砂的化学组成和微观形貌进行分析,运用改进的煮沸试验对沥青在铁尾矿表面的黏附率进行定量分析,并利用分子动力学模拟计算铁尾矿-沥青界面的黏附能,最后基于灰色关联法分析微观测试结果与宏观黏附率的关联度.结果表明:铁尾矿砂、石灰岩和玄武岩的主要化学成分、矿物组成差异较大,铁尾矿砂金属氧化物含量较高,表面存在金属光泽,棱角丰富,铁尾矿与沥青的界面黏附能及沥青在铁尾矿表面的黏附率介于石灰岩和玄武岩之间,微观测试结果与宏观黏附率的关联度排序(从大到小)为表观形貌、CaO+MgO含量、钠长石含量、界面黏附能,可见此铁尾矿与沥青黏附性较好,满足工程要求.研究结果可为铁尾矿在沥青面层的应用奠定基础.
Study on the Interface Adhesion of Iron Tailings and Asphalt Based on Macro-micro Test Method
As a new material,the addition of iron tailings to asphalt will produce a new interface,and its interface adhe-sivity with asphalt directly affects the road performance of asphalt mixture.In order to reveal the adhesion mechanism of iron tailings-asphalt interface,the chemical composition and microstructure of iron tailings sand were analyzed by X-ray fluorescence spectrometer,X-ray diffractometer and scanning electron microscope.The adhesion rate of asphalt on the surface of iron tailings was quantitatively analyzed by improved boiling test,and the adhesion energy of iron tailings-asphalt interface was calculated by molecular dynamics simulation.Finally,the correlation degree between microscopic test results and macroscopic adhesion rate was analyzed based on grey correlation method.The results show that the main chemical composition and mineral composition of iron tailings sand,limestone and basalt are quite different.The content of metal oxide in iron tailings sand is higher,the sur-face has metal luster,rich edges and corners.The interface adhesion energy between iron tailings and asphalt,the adhesion rate of asphalt on the surface of iron tailings are between those of limestone and basalt.The correlation degree between the micro-scopic test results and the macroscopic adhesion rate(from large to small)is the apparent morphology,CaO+MgO content,al-bite content,and interface adhesion energy.It can be seen that the iron tailings have a good adhesivity with asphalt and meet the engineering requirements.The research results can lay a foundation for the application of iron tailings in asphalt surface layer.

iron tailings sandasphaltadhesivitymicroscopic experimentboiling experimentgrey correlation analysis

崔亚宁、司春棣、李松、郭彬、崔巧萱

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石家庄铁道大学交通运输学院,河北 石家庄 050043

河北省交通安全与控制重点实验室,河北 石家庄 050043

省部共建交通工程结构力学行为与系统安全国家重点实验室,河北 石家庄 050043

铁尾矿砂 沥青 黏附性 微观实验 煮沸实验 灰色关联分析

国家自然科学基金项目河北省重点研发计划项目河北省自然科学基金项目

5237845521373801DE2022210054

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(6)